Crystal and Molecular Structure of 2,3,7,8,12,13,17,18-Octaethylporphinatooxovanadium(IV)

Frank S. Molinaro, James A Ibers*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

63 Scopus citations

Abstract

The structure of 2,3,7,8,12,13,17,18-octaethylporphinatooxovanadium(IV) has been determined from three-dimensional x-ray diffraction data. The complex crystallizes in the monoclinic space group C2h 5-P21/c with four molecules in a unit cell of dimensions a = 14.334 (3), b = 23.061 (8), c = 9.815 (2) Å, β = 104.18 (2)°. The structure was solved by direct methods. Least-squares refinement has led to a final value of the conventional R index (on F0 2) of 0.084 based on 6482 reflections (including F0 2 ≤ 0). The vanadium atom is found to be 0.543 Å above the plane of the four nitrogen atoms. The average V-N bond distance is 2.102 (6) and the V-O bond length is 1.620 (2) Å. The porphyrin itself is slightly nonplanar.

Original languageEnglish (US)
Pages (from-to)2278-2283
Number of pages6
JournalInorganic Chemistry
Volume15
Issue number9
DOIs
StatePublished - Sep 1 1976

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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