Crystal and Molecular Structure of Hydrido(dinitrogen)bis[phenyl(di-tert-butyl)phosphine]-rhodium(I)

P. R. Hoffman, T. Yoshida, T. Okano, S. Otsuka, James A. Ibers

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40 Scopus citations

Abstract

The structure of hydrido(dinitrogen)bis[phenyl(di-tert-butyl)phosphine]rhodium(I), RhH(N2)[P(C6H5)(C4H9)2]2, has been determined crystallographically. The complex possesses a typical four-coordinate planar geometry about Rh with a slight bending of the phosphine groups toward the hydrido ligand (P-Rh-P = 168.12 (3)°). A linear H-Rh-N-N arrangement is required by the crystallographically imposed twofold axis. The compound crystallizes in space group C2h6-C2/c of the monoclinic system with four formula units in a cell of dimensions a = 22.187 (2) Å, b = 8.340 (1) Å, c = 15.979 (2) Å, and β = 93.108 (6)°. Important distances are Rh-P = 2.297 (1) Å, Rh-H = 1.66 (5) Å, Rh-N = 1.970 (4) Å, and N-N = 1.074 (7) Å. The structural data were refined by full-matrix least-squares methods to a conventional R index of 0.034 based on those 2760 reflections having F02 > 3σ(F02).

Original languageEnglish (US)
Pages (from-to)2462-2466
Number of pages5
JournalInorganic chemistry
Volume15
Issue number10
DOIs
StatePublished - Oct 1 1976

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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