Crystal and molecular structure of titanium (IV) ethoxide

James A. Ibers*

*Corresponding author for this work

Research output: Contribution to journalArticle

128 Scopus citations

Abstract

BOTH speculation and controversy on the stereochemistry of the trimeric titanium (IV) alkoxides1-6 have followed the discovery6 of their trimeric nature in solution. Opinions have differed on which structure is stereochemically reasonable and on which structure will account in a natural way for the hydrolysis products of titanium (IV) alkoxides, the so-called titanium oxide-alkoxides of composition Ti3(x+1)O4x(OR) 4(x+3). These titanium oxide-alkoxides have been characterized, at least for x = 1 and x = 3, as solids1. The purpose of this communication is to indicate that titanium (IV) ethoxide is a tetramer in the solid, and hence that this long-awaited X-ray analysis of a titanium (IV) alkoxide not only fails to confirm one of the proposed structures, but also makes unreasonable the assumption, implicit in much of the recent discussions, that the species in solution are identical with those precipitated from solution.

Original languageEnglish (US)
Pages (from-to)686-687
Number of pages2
JournalNature
Volume197
Issue number4868
DOIs
StatePublished - Dec 1 1963

ASJC Scopus subject areas

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