Crystal growth and co-substitution in (Mg1-xFex)(Mo2-xVx)O7 (0.13≤x≤0.47) with (V/Mo)=O oxo double bonds

Xiandong Wang; Alexander J. Norquist; Jason Pless; Charlotte L. Stern; Douglas A. Vander Griend; Kenneth R. Poeppelmeier

doi:10.1016/S0925-8388(02)00178-0

Crystal growth and co-substitution in (Mg_1-xFe_x)(Mo_2-xV_x)O₇ (0.13≤x≤0.47) with (V/Mo)=O oxo double bonds

Xiandong Wang, Alexander J. Norquist, Jason Pless, Charlotte L. Stern, Douglas A. Vander Griend, Kenneth R. Poeppelmeier^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The solid solution crystals of Mg_1-xFe_xMo_2-xV_xO₇ (0.13≤x≤0.47) grown from MgO-Fe₂O₃-V₂O₅-MoO₃ melts were discussed. Its structure was analyzed by x-ray single crystal diffraction and the results were compared with FeVMoO₇ and MgMo₂O₇. It was found that the structure contains (V/Mo)=O oxo double bonds similar to MgMo₂O₇ and FeVMoO₇.

Original language	English (US)
Pages (from-to)	26-31
Number of pages	6
Journal	Journal of Alloys and Compounds
Volume	338
Issue number	1-2 SPEC.
DOIs	https://doi.org/10.1016/S0925-8388(02)00178-0
State	Published - May 16 2002

Funding

The authors thank Dr. Larry Cirjak and acknowledge a Research Award from BP America. This work was also supported by the National Science Foundation, Solid State Chemistry (DMR-9412971 and DMR-9727516) and made use of the Central Facilities supported by MRSEC program of the National Science Foundation (DMR-0076097) at the Materials Science Center of Northwestern University, and the EMSI program of the NSF and the Department of Energy (CHE-9810378) at the Northwestern University Institute for Environmental Catalysis.

Keywords

Crystal growth
Metal oxo double bond
Molybdate
Vanadate

ASJC Scopus subject areas

Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

Access to Document

10.1016/S0925-8388(02)00178-0

Cite this

@article{19005d5c6443411e872b11355fce5b1c,

title = "Crystal growth and co-substitution in (Mg1-xFex)(Mo2-xVx)O7 (0.13≤x≤0.47) with (V/Mo)=O oxo double bonds",

abstract = "The solid solution crystals of Mg1-xFexMo2-xVxO7 (0.13≤x≤0.47) grown from MgO-Fe2O3-V2O5-MoO3 melts were discussed. Its structure was analyzed by x-ray single crystal diffraction and the results were compared with FeVMoO7 and MgMo2O7. It was found that the structure contains (V/Mo)=O oxo double bonds similar to MgMo2O7 and FeVMoO7.",

keywords = "Crystal growth, Metal oxo double bond, Molybdate, Vanadate",

author = "Xiandong Wang and Norquist, {Alexander J.} and Jason Pless and Stern, {Charlotte L.} and {Vander Griend}, {Douglas A.} and Poeppelmeier, {Kenneth R.}",

note = "Funding Information: The authors thank Dr. Larry Cirjak and acknowledge a Research Award from BP America. This work was also supported by the National Science Foundation, Solid State Chemistry (DMR-9412971 and DMR-9727516) and made use of the Central Facilities supported by MRSEC program of the National Science Foundation (DMR-0076097) at the Materials Science Center of Northwestern University, and the EMSI program of the NSF and the Department of Energy (CHE-9810378) at the Northwestern University Institute for Environmental Catalysis. ",

year = "2002",

month = may,

day = "16",

doi = "10.1016/S0925-8388(02)00178-0",

language = "English (US)",

volume = "338",

pages = "26--31",

journal = "Journal of Alloys and Compounds",

issn = "0925-8388",

publisher = "Elsevier B.V.",

number = "1-2 SPEC.",

}

TY - JOUR

T1 - Crystal growth and co-substitution in (Mg1-xFex)(Mo2-xVx)O7 (0.13≤x≤0.47) with (V/Mo)=O oxo double bonds

AU - Wang, Xiandong

AU - Norquist, Alexander J.

AU - Pless, Jason

AU - Stern, Charlotte L.

AU - Vander Griend, Douglas A.

AU - Poeppelmeier, Kenneth R.

N1 - Funding Information: The authors thank Dr. Larry Cirjak and acknowledge a Research Award from BP America. This work was also supported by the National Science Foundation, Solid State Chemistry (DMR-9412971 and DMR-9727516) and made use of the Central Facilities supported by MRSEC program of the National Science Foundation (DMR-0076097) at the Materials Science Center of Northwestern University, and the EMSI program of the NSF and the Department of Energy (CHE-9810378) at the Northwestern University Institute for Environmental Catalysis.

PY - 2002/5/16

Y1 - 2002/5/16

N2 - The solid solution crystals of Mg1-xFexMo2-xVxO7 (0.13≤x≤0.47) grown from MgO-Fe2O3-V2O5-MoO3 melts were discussed. Its structure was analyzed by x-ray single crystal diffraction and the results were compared with FeVMoO7 and MgMo2O7. It was found that the structure contains (V/Mo)=O oxo double bonds similar to MgMo2O7 and FeVMoO7.

AB - The solid solution crystals of Mg1-xFexMo2-xVxO7 (0.13≤x≤0.47) grown from MgO-Fe2O3-V2O5-MoO3 melts were discussed. Its structure was analyzed by x-ray single crystal diffraction and the results were compared with FeVMoO7 and MgMo2O7. It was found that the structure contains (V/Mo)=O oxo double bonds similar to MgMo2O7 and FeVMoO7.

KW - Crystal growth

KW - Metal oxo double bond

KW - Molybdate

KW - Vanadate

UR - http://www.scopus.com/inward/record.url?scp=0037118121&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037118121&partnerID=8YFLogxK

U2 - 10.1016/S0925-8388(02)00178-0

DO - 10.1016/S0925-8388(02)00178-0

M3 - Article

AN - SCOPUS:0037118121

SN - 0925-8388

VL - 338

SP - 26

EP - 31

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

IS - 1-2 SPEC.

ER -