Crystal growth of Ag3 M OxF6-x (M = V, x = 2; M = Mo, x = 3)

Julia M. Chamberlain; Thomas A. Albrecht; Julien Lesage; Frédéric Sauvage; Charlotte L. Stern; Kenneth R. Poeppelmeier

doi:10.1021/cg100890e

Crystal growth of Ag₃ M O_xF_6-x (M = V, x = 2; M = Mo, x = 3)

Julia M. Chamberlain, Thomas A. Albrecht, Julien Lesage, Frédéric Sauvage, Charlotte L. Stern, Kenneth R. Poeppelmeier

Chemistry

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

Understanding the complex relationship between synthesis conditions, in particular temperature and composition, led to single crystals of the cryolite type phases Ag₃MoO₃F₃ and Ag₃VO ₂F₄. These crystals form in a reversible thermodynamic process from dissolved species when the solution is heated. Single crystal structural data reveal the Mo⁶⁺ cation distorted toward facially coordinated oxides for Ag₃MoO₃F₃, and the V⁵⁺ cation toward the edge of the cis-oxide positions for Ag ₃VO₂F₄. Local ordering of oxide and fluoride ligands is observed for both structures.

Original language	English (US)
Pages (from-to)	4868-4873
Number of pages	6
Journal	Crystal Growth and Design
Volume	10
Issue number	11
DOIs	https://doi.org/10.1021/cg100890e
State	Published - Nov 3 2010

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Crystal growth of Ag3 M OxF6-x (M = V, x = 2; M = Mo, x = 3)",

abstract = "Understanding the complex relationship between synthesis conditions, in particular temperature and composition, led to single crystals of the cryolite type phases Ag3MoO3F3 and Ag3VO 2F4. These crystals form in a reversible thermodynamic process from dissolved species when the solution is heated. Single crystal structural data reveal the Mo6+ cation distorted toward facially coordinated oxides for Ag3MoO3F3, and the V5+ cation toward the edge of the cis-oxide positions for Ag 3VO2F4. Local ordering of oxide and fluoride ligands is observed for both structures.",

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T1 - Crystal growth of Ag3 M OxF6-x (M = V, x = 2; M = Mo, x = 3)

AU - Chamberlain, Julia M.

AU - Albrecht, Thomas A.

AU - Lesage, Julien

AU - Sauvage, Frédéric

AU - Stern, Charlotte L.

AU - Poeppelmeier, Kenneth R.

PY - 2010/11/3

Y1 - 2010/11/3

N2 - Understanding the complex relationship between synthesis conditions, in particular temperature and composition, led to single crystals of the cryolite type phases Ag3MoO3F3 and Ag3VO 2F4. These crystals form in a reversible thermodynamic process from dissolved species when the solution is heated. Single crystal structural data reveal the Mo6+ cation distorted toward facially coordinated oxides for Ag3MoO3F3, and the V5+ cation toward the edge of the cis-oxide positions for Ag 3VO2F4. Local ordering of oxide and fluoride ligands is observed for both structures.

AB - Understanding the complex relationship between synthesis conditions, in particular temperature and composition, led to single crystals of the cryolite type phases Ag3MoO3F3 and Ag3VO 2F4. These crystals form in a reversible thermodynamic process from dissolved species when the solution is heated. Single crystal structural data reveal the Mo6+ cation distorted toward facially coordinated oxides for Ag3MoO3F3, and the V5+ cation toward the edge of the cis-oxide positions for Ag 3VO2F4. Local ordering of oxide and fluoride ligands is observed for both structures.

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Crystal growth of Ag₃ M O_xF_6-x (M = V, x = 2; M = Mo, x = 3)

Abstract

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