Crystal growth, structure, and properties of manganese orthovanadate Mn3(VO4)2

X. Wang; Z. Liu; A. Ambrosini; A. Maignan; C. L. Stern; K. R. Poeppelmeier; V. P. Dravid

doi:10.1016/S1293-2558(00)00104-7

Crystal growth, structure, and properties of manganese orthovanadate Mn₃(VO₄)₂

X. Wang, Z. Liu, A. Ambrosini, A. Maignan, C. L. Stern, K. R. Poeppelmeier^*, V. P. Dravid

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Manganese orthovanadate Mn₃(VO₄)₂ single crystals were grown for the first time from a flux of MnO/V₂O₅/MoO₃. The flux and oxygen partial pressure used are the key factors for the crystal growth and prevention of the oxidation of Mn²⁺ and the reduction of V⁵⁺ during the crystallization process. The reduction and oxidation chemistry of Mn₃(VO₄)₂ was studied. Mn₃(VO₄)₂ is isostructural with magnesium orthovanadate Mg₃(VO₄)₂, orthorhombic, space group Cmca, a = 6.247(1) Å, b = 11.728(2) Å, c = 8.491(2) Å and Z = 4, as determined by single crystal X-ray diffraction. Because it is a Mn²⁺ deficient spinel structure there are two-dimensional sheets of Mn²⁺O₆ octahedra within the structure which show unusual ferrimagnetic properties. (C) 2000 Editions scientifiques et medicales Elsevier SAS.

Original language	English (US)
Pages (from-to)	99-107
Number of pages	9
Journal	Solid State Sciences
Volume	2
Issue number	1
DOIs	https://doi.org/10.1016/S1293-2558(00)00104-7
State	Published - 2000

Keywords

Cation deficient spinel
Crystal growth
Magnetic susceptibility
Manganese orthovanadate

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1016/S1293-2558(00)00104-7

Cite this

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title = "Crystal growth, structure, and properties of manganese orthovanadate Mn3(VO4)2",

abstract = "Manganese orthovanadate Mn3(VO4)2 single crystals were grown for the first time from a flux of MnO/V2O5/MoO3. The flux and oxygen partial pressure used are the key factors for the crystal growth and prevention of the oxidation of Mn2+ and the reduction of V5+ during the crystallization process. The reduction and oxidation chemistry of Mn3(VO4)2 was studied. Mn3(VO4)2 is isostructural with magnesium orthovanadate Mg3(VO4)2, orthorhombic, space group Cmca, a = 6.247(1) {\AA}, b = 11.728(2) {\AA}, c = 8.491(2) {\AA} and Z = 4, as determined by single crystal X-ray diffraction. Because it is a Mn2+ deficient spinel structure there are two-dimensional sheets of Mn2+O6 octahedra within the structure which show unusual ferrimagnetic properties. (C) 2000 Editions scientifiques et medicales Elsevier SAS.",

keywords = "Cation deficient spinel, Crystal growth, Magnetic susceptibility, Manganese orthovanadate",

author = "X. Wang and Z. Liu and A. Ambrosini and A. Maignan and Stern, {C. L.} and Poeppelmeier, {K. R.} and Dravid, {V. P.}",

note = "Funding Information: The authors wish to thank Dr. Larry Cirjak and acknowledge a Research Award from BP America. This work was also supported by the National Science Foundation (NSF) (DMR-9727516) and made use of the Central Facilities, supported by the NSF, at the Materials Research Center of Northwestern University (DMR-9632472), and the EMSI program of the NSF and Department of Energy (CHE-9810378) at the Northwestern University Institute for Environmental Catalysis.",

year = "2000",

doi = "10.1016/S1293-2558(00)00104-7",

language = "English (US)",

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pages = "99--107",

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publisher = "Elsevier Masson SAS",

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TY - JOUR

T1 - Crystal growth, structure, and properties of manganese orthovanadate Mn3(VO4)2

AU - Wang, X.

AU - Liu, Z.

AU - Ambrosini, A.

AU - Maignan, A.

AU - Stern, C. L.

AU - Poeppelmeier, K. R.

AU - Dravid, V. P.

N1 - Funding Information: The authors wish to thank Dr. Larry Cirjak and acknowledge a Research Award from BP America. This work was also supported by the National Science Foundation (NSF) (DMR-9727516) and made use of the Central Facilities, supported by the NSF, at the Materials Research Center of Northwestern University (DMR-9632472), and the EMSI program of the NSF and Department of Energy (CHE-9810378) at the Northwestern University Institute for Environmental Catalysis.

PY - 2000

Y1 - 2000

N2 - Manganese orthovanadate Mn3(VO4)2 single crystals were grown for the first time from a flux of MnO/V2O5/MoO3. The flux and oxygen partial pressure used are the key factors for the crystal growth and prevention of the oxidation of Mn2+ and the reduction of V5+ during the crystallization process. The reduction and oxidation chemistry of Mn3(VO4)2 was studied. Mn3(VO4)2 is isostructural with magnesium orthovanadate Mg3(VO4)2, orthorhombic, space group Cmca, a = 6.247(1) Å, b = 11.728(2) Å, c = 8.491(2) Å and Z = 4, as determined by single crystal X-ray diffraction. Because it is a Mn2+ deficient spinel structure there are two-dimensional sheets of Mn2+O6 octahedra within the structure which show unusual ferrimagnetic properties. (C) 2000 Editions scientifiques et medicales Elsevier SAS.

AB - Manganese orthovanadate Mn3(VO4)2 single crystals were grown for the first time from a flux of MnO/V2O5/MoO3. The flux and oxygen partial pressure used are the key factors for the crystal growth and prevention of the oxidation of Mn2+ and the reduction of V5+ during the crystallization process. The reduction and oxidation chemistry of Mn3(VO4)2 was studied. Mn3(VO4)2 is isostructural with magnesium orthovanadate Mg3(VO4)2, orthorhombic, space group Cmca, a = 6.247(1) Å, b = 11.728(2) Å, c = 8.491(2) Å and Z = 4, as determined by single crystal X-ray diffraction. Because it is a Mn2+ deficient spinel structure there are two-dimensional sheets of Mn2+O6 octahedra within the structure which show unusual ferrimagnetic properties. (C) 2000 Editions scientifiques et medicales Elsevier SAS.

KW - Cation deficient spinel

KW - Crystal growth

KW - Magnetic susceptibility

KW - Manganese orthovanadate

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Crystal growth, structure, and properties of manganese orthovanadate Mn₃(VO₄)₂

Abstract

Keywords

ASJC Scopus subject areas

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CSD 1773397: Experimental Crystal Structure Determination

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Crystal growth, structure, and properties of manganese orthovanadate Mn3(VO4)2

Abstract

Keywords

ASJC Scopus subject areas

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Datasets

CSD 1773397: Experimental Crystal Structure Determination

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Crystal growth, structure, and properties of manganese orthovanadate Mn₃(VO₄)₂