Crystal to crystal guest exchange in a mixed ligand metal-organic framework

Andrew P. Nelson; Damon A. Parrish; Lee R. Cambrea; Lawrence C. Baldwin; Nirupam J. Trivedi; Karen L. Mulfort; Omar K. Farha; Joseph T. Hupp

doi:10.1021/cg900735n

Crystal to crystal guest exchange in a mixed ligand metal-organic framework

Andrew P. Nelson, Damon A. Parrish, Lee R. Cambrea, Lawrence C. Baldwin, Nirupam J. Trivedi, Karen L. Mulfort, Omar K. Farha, Joseph T. Hupp

Chemistry

Research output: Contribution to journal › Article › peer-review

41 Scopus citations

Abstract

The occluded solvent in a mixed ligand metal-organic framework has been displaced by n-hexanol, chloroform, and nitrobenzene in a crystal to crystal guest exchange. The X-ray structures of the three new solvent adducts of Zn ₂NDC₂DPNI₂ reveal the complete replacement of N' ,N-dimethylformamide with the new guest. Structural changes to the framework geometry in response to the size of the incoming guest are also exhibited. These new frameworks are characterized by powder X-ray diffraction, thermal gravimetric analysis coupled with infrared spectroscopy, and cross-polarization magic angle spinning NMR.

Original language	English (US)
Pages (from-to)	4588-4591
Number of pages	4
Journal	Crystal Growth and Design
Volume	9
Issue number	11
DOIs	https://doi.org/10.1021/cg900735n
State	Published - Nov 4 2009

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1021/cg900735n

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title = "Crystal to crystal guest exchange in a mixed ligand metal-organic framework",

abstract = "The occluded solvent in a mixed ligand metal-organic framework has been displaced by n-hexanol, chloroform, and nitrobenzene in a crystal to crystal guest exchange. The X-ray structures of the three new solvent adducts of Zn 2NDC2DPNI2 reveal the complete replacement of N' ,N-dimethylformamide with the new guest. Structural changes to the framework geometry in response to the size of the incoming guest are also exhibited. These new frameworks are characterized by powder X-ray diffraction, thermal gravimetric analysis coupled with infrared spectroscopy, and cross-polarization magic angle spinning NMR.",

author = "Nelson, {Andrew P.} and Parrish, {Damon A.} and Cambrea, {Lee R.} and Baldwin, {Lawrence C.} and Trivedi, {Nirupam J.} and Mulfort, {Karen L.} and Farha, {Omar K.} and Hupp, {Joseph T.}",

year = "2009",

month = nov,

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doi = "10.1021/cg900735n",

language = "English (US)",

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journal = "Crystal Growth and Design",

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T1 - Crystal to crystal guest exchange in a mixed ligand metal-organic framework

AU - Nelson, Andrew P.

AU - Parrish, Damon A.

AU - Cambrea, Lee R.

AU - Baldwin, Lawrence C.

AU - Trivedi, Nirupam J.

AU - Mulfort, Karen L.

AU - Farha, Omar K.

AU - Hupp, Joseph T.

PY - 2009/11/4

Y1 - 2009/11/4

N2 - The occluded solvent in a mixed ligand metal-organic framework has been displaced by n-hexanol, chloroform, and nitrobenzene in a crystal to crystal guest exchange. The X-ray structures of the three new solvent adducts of Zn 2NDC2DPNI2 reveal the complete replacement of N' ,N-dimethylformamide with the new guest. Structural changes to the framework geometry in response to the size of the incoming guest are also exhibited. These new frameworks are characterized by powder X-ray diffraction, thermal gravimetric analysis coupled with infrared spectroscopy, and cross-polarization magic angle spinning NMR.

AB - The occluded solvent in a mixed ligand metal-organic framework has been displaced by n-hexanol, chloroform, and nitrobenzene in a crystal to crystal guest exchange. The X-ray structures of the three new solvent adducts of Zn 2NDC2DPNI2 reveal the complete replacement of N' ,N-dimethylformamide with the new guest. Structural changes to the framework geometry in response to the size of the incoming guest are also exhibited. These new frameworks are characterized by powder X-ray diffraction, thermal gravimetric analysis coupled with infrared spectroscopy, and cross-polarization magic angle spinning NMR.

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DO - 10.1021/cg900735n

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JO - Crystal Growth and Design

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ER -

Crystal to crystal guest exchange in a mixed ligand metal-organic framework

Abstract

ASJC Scopus subject areas

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CCDC 756987: Experimental Crystal Structure Determination

CCDC 756988: Experimental Crystal Structure Determination

CCDC 756986: Experimental Crystal Structure Determination

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Crystal to crystal guest exchange in a mixed ligand metal-organic framework

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 756987: Experimental Crystal Structure Determination

CCDC 756988: Experimental Crystal Structure Determination

CCDC 756986: Experimental Crystal Structure Determination

Cite this