Abstract
Freeze-frame: Octahedral and square-planar structural isomers, representing the two "end states" in a hemilabile ligand bond-breaking isomerization reaction, have been characterized in solution by spectroscopic methods and in the solid state by X-ray crystallography (see picture: Nigreen, Cgray, Porange, Nblue, Syellow).
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1469-1472 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 51 |
| Issue number | 6 |
| DOIs | |
| State | Published - Feb 6 2012 |
Keywords
- bond-breaking isomers
- coordination modes
- exchange processes
- hemilabile ligands
- nickel
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
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Dive into the research topics of 'Crystallographic snapshots of the bond-breaking isomerization reactions involving nickel(II) complexes with hemilabile ligands'. Together they form a unique fingerprint.Datasets
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CCDC 851139: Experimental Crystal Structure Determination
MacHan, C. W. (Contributor), Lifschitz, A. M. (Creator), Stern, C. L. (Creator), Sarjeant, A. A. (Creator) & Mirkin, C. A. (Creator), Cambridge Crystallographic Data Centre, 2012
DOI: 10.5517/ccxkp37, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccxkp37&sid=DataCite
Dataset
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CCDC 851134: Experimental Crystal Structure Determination
MacHan, C. W. (Contributor), Lifschitz, A. M. (Creator), Stern, C. L. (Creator), Sarjeant, A. A. (Creator) & Mirkin, C. A. (Creator), Cambridge Crystallographic Data Centre, 2012
DOI: 10.5517/ccxkny1, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccxkny1&sid=DataCite
Dataset
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CCDC 851135: Experimental Crystal Structure Determination
MacHan, C. W. (Contributor), Lifschitz, A. M. (Creator), Stern, C. L. (Creator), Sarjeant, A. A. (Creator) & Mirkin, C. A. (Creator), Cambridge Crystallographic Data Centre, 2012
DOI: 10.5517/ccxknz2, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccxknz2&sid=DataCite
Dataset