Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: New methods for constructing porous materials

Andrea N. Alsobrook; Brad G. Hauser; Joseph T. Hupp; Evgeny V. Alekseev; Wulf Depmeier; Thomas E. Albrecht-Schmitt

doi:10.1039/c0cc03507f

Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: New methods for constructing porous materials

Andrea N. Alsobrook, Brad G. Hauser, Joseph T. Hupp, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht-Schmitt

Chemistry

Research output: Contribution to journal › Article › peer-review

106 Scopus citations

Abstract

Four heterobimetallic U(vi)/M(ii) (M = Mn, Co, Cd) carboxyphosphonates have been synthesized. M₂[(UO₂)₆(PO ₃CH₂CO₂)₃O₃(OH)(H ₂O)₂]·16H₂O (M = Mn(ii), Co(ii), and Cd(ii)) adopt cubic three-dimensional network structures with large cavities approximately 16 in diameter that are filled with co-crystallized water molecules. [Cd₃(UO₂)₆(PO₃CH ₂CO₂)₆(H₂O)₁₃] ·6H₂O forms a rhombohedral channel structure with hydrated Cd(ii) within the channels. The cubic compound (Co) displays differential gas absorption with a surface area for CO₂ uptake of 40 m² g^-1 at 273 K, and no uptake of N₂ at 77 K.

Original language	English (US)
Pages (from-to)	9167-9169
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	48
DOIs	https://doi.org/10.1039/c0cc03507f
State	Published - Dec 28 2010

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
General Chemistry
Catalysis

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10.1039/c0cc03507f

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title = "Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: New methods for constructing porous materials",

abstract = "Four heterobimetallic U(vi)/M(ii) (M = Mn, Co, Cd) carboxyphosphonates have been synthesized. M2[(UO2)6(PO 3CH2CO2)3O3(OH)(H 2O)2]·16H2O (M = Mn(ii), Co(ii), and Cd(ii)) adopt cubic three-dimensional network structures with large cavities approximately 16 in diameter that are filled with co-crystallized water molecules. [Cd3(UO2)6(PO3CH 2CO2)6(H2O)13] ·6H2O forms a rhombohedral channel structure with hydrated Cd(ii) within the channels. The cubic compound (Co) displays differential gas absorption with a surface area for CO2 uptake of 40 m2 g-1 at 273 K, and no uptake of N2 at 77 K.",

author = "Alsobrook, {Andrea N.} and Hauser, {Brad G.} and Hupp, {Joseph T.} and Alekseev, {Evgeny V.} and Wulf Depmeier and Albrecht-Schmitt, {Thomas E.}",

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doi = "10.1039/c0cc03507f",

language = "English (US)",

volume = "46",

pages = "9167--9169",

journal = "Chemical Communications",

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TY - JOUR

T1 - Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate

T2 - New methods for constructing porous materials

AU - Alsobrook, Andrea N.

AU - Hauser, Brad G.

AU - Hupp, Joseph T.

AU - Alekseev, Evgeny V.

AU - Depmeier, Wulf

AU - Albrecht-Schmitt, Thomas E.

PY - 2010/12/28

Y1 - 2010/12/28

N2 - Four heterobimetallic U(vi)/M(ii) (M = Mn, Co, Cd) carboxyphosphonates have been synthesized. M2[(UO2)6(PO 3CH2CO2)3O3(OH)(H 2O)2]·16H2O (M = Mn(ii), Co(ii), and Cd(ii)) adopt cubic three-dimensional network structures with large cavities approximately 16 in diameter that are filled with co-crystallized water molecules. [Cd3(UO2)6(PO3CH 2CO2)6(H2O)13] ·6H2O forms a rhombohedral channel structure with hydrated Cd(ii) within the channels. The cubic compound (Co) displays differential gas absorption with a surface area for CO2 uptake of 40 m2 g-1 at 273 K, and no uptake of N2 at 77 K.

AB - Four heterobimetallic U(vi)/M(ii) (M = Mn, Co, Cd) carboxyphosphonates have been synthesized. M2[(UO2)6(PO 3CH2CO2)3O3(OH)(H 2O)2]·16H2O (M = Mn(ii), Co(ii), and Cd(ii)) adopt cubic three-dimensional network structures with large cavities approximately 16 in diameter that are filled with co-crystallized water molecules. [Cd3(UO2)6(PO3CH 2CO2)6(H2O)13] ·6H2O forms a rhombohedral channel structure with hydrated Cd(ii) within the channels. The cubic compound (Co) displays differential gas absorption with a surface area for CO2 uptake of 40 m2 g-1 at 273 K, and no uptake of N2 at 77 K.

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DO - 10.1039/c0cc03507f

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SN - 1359-7345

VL - 46

SP - 9167

EP - 9169

JO - Chemical Communications

JF - Chemical Communications

IS - 48

ER -

Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: New methods for constructing porous materials

Abstract

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CCDC 794933: Experimental Crystal Structure Determination

CCDC 794932: Experimental Crystal Structure Determination

CCDC 794934: Experimental Crystal Structure Determination

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Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: New methods for constructing porous materials

Abstract

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Datasets

CCDC 794933: Experimental Crystal Structure Determination

CCDC 794932: Experimental Crystal Structure Determination

CCDC 794934: Experimental Crystal Structure Determination

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