Cu(tatbp)I and [Cu(tatbp)]3 [ReO4l2 · (C10H7C1): Long-range CuCu couplings in quasi one-dimensional molecular metals

Martin R. Godfrey*, Kwangkyoung Liou, Timothy P. Newcomb, William P. Halperin, Brian M. Hoffman, James A. Ibers

*Corresponding author for this work

Research output: Contribution to journalArticle

6 Scopus citations

Abstract

Comparison of the properties of the title compounds indicates that the strong CuCu coupling along the Cu+2 chains within the conducting stacks of Cu(tatbp)I and Cu(pc)I has a minimal contribution from direct near-neighbor interactions and arises primarily from long-range carrier-mediated interactions. Anomalous g-shifts observed at low temperatures for Cu(tatbp)I are found to be dependent on magnetic field.

Original languageEnglish (US)
Pages (from-to)51-58
Number of pages8
JournalSynthetic Metals
Volume29
Issue number2-3
DOIs
StatePublished - Mar 21 1989

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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