Cu(tatbp)I and [Cu(tatbp)]3 [ReO4l2 · (C10H7C1): Long-range CuCu couplings in quasi one-dimensional molecular metals

Martin R. Godfrey; Kwangkyoung Liou; Timothy P. Newcomb; William P. Halperin; Brian M. Hoffman; James A. Ibers

doi:10.1016/0379-6779(89)90878-3

Cu(tatbp)I and [Cu(tatbp)]₃ [ReO₄l₂ · (C₁₀H₇C1): Long-range CuCu couplings in quasi one-dimensional molecular metals

Martin R. Godfrey^*, Kwangkyoung Liou, Timothy P. Newcomb, William P. Halperin, Brian M. Hoffman, James A. Ibers

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Comparison of the properties of the title compounds indicates that the strong CuCu coupling along the Cu⁺² chains within the conducting stacks of Cu(tatbp)I and Cu(pc)I has a minimal contribution from direct near-neighbor interactions and arises primarily from long-range carrier-mediated interactions. Anomalous g-shifts observed at low temperatures for Cu(tatbp)I are found to be dependent on magnetic field.

Original language	English (US)
Pages (from-to)	51-58
Number of pages	8
Journal	Synthetic Metals
Volume	29
Issue number	2-3
DOIs	https://doi.org/10.1016/0379-6779(89)90878-3
State	Published - Mar 21 1989

Funding

ACKNOWLEDGEMENTS This work benefited from the collaboration with Professor M. Poirler and G. Qulrlon. It was supported by the NSF Solid-State Chemistry Program (DMR 85-19233, BMH) and by the Northwestern University Materials Research Center under the NSF-MRL Program (DMR 85-20280).

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

Access to Document

10.1016/0379-6779(89)90878-3

Cite this

@article{1630aa620db144ada7cd5f34ec26284d,

title = "Cu(tatbp)I and [Cu(tatbp)]3 [ReO4l2 · (C10H7C1): Long-range CuCu couplings in quasi one-dimensional molecular metals",

abstract = "Comparison of the properties of the title compounds indicates that the strong CuCu coupling along the Cu+2 chains within the conducting stacks of Cu(tatbp)I and Cu(pc)I has a minimal contribution from direct near-neighbor interactions and arises primarily from long-range carrier-mediated interactions. Anomalous g-shifts observed at low temperatures for Cu(tatbp)I are found to be dependent on magnetic field.",

author = "Godfrey, {Martin R.} and Kwangkyoung Liou and Newcomb, {Timothy P.} and Halperin, {William P.} and Hoffman, {Brian M.} and Ibers, {James A.}",

note = "Funding Information: ACKNOWLEDGEMENTS This work benefited from the collaboration with Professor M. Poirler and G. Qulrlon. It was supported by the NSF Solid-State Chemistry Program (DMR 85-19233, BMH) and by the Northwestern University Materials Research Center under the NSF-MRL Program (DMR 85-20280).",

year = "1989",

month = mar,

day = "21",

doi = "10.1016/0379-6779(89)90878-3",

language = "English (US)",

volume = "29",

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journal = "Synthetic Metals",

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publisher = "Elsevier BV",

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TY - JOUR

T1 - Cu(tatbp)I and [Cu(tatbp)]3 [ReO4l2 · (C10H7C1)

T2 - Long-range CuCu couplings in quasi one-dimensional molecular metals

AU - Godfrey, Martin R.

AU - Liou, Kwangkyoung

AU - Newcomb, Timothy P.

AU - Halperin, William P.

AU - Hoffman, Brian M.

AU - Ibers, James A.

N1 - Funding Information: ACKNOWLEDGEMENTS This work benefited from the collaboration with Professor M. Poirler and G. Qulrlon. It was supported by the NSF Solid-State Chemistry Program (DMR 85-19233, BMH) and by the Northwestern University Materials Research Center under the NSF-MRL Program (DMR 85-20280).

PY - 1989/3/21

Y1 - 1989/3/21

N2 - Comparison of the properties of the title compounds indicates that the strong CuCu coupling along the Cu+2 chains within the conducting stacks of Cu(tatbp)I and Cu(pc)I has a minimal contribution from direct near-neighbor interactions and arises primarily from long-range carrier-mediated interactions. Anomalous g-shifts observed at low temperatures for Cu(tatbp)I are found to be dependent on magnetic field.

AB - Comparison of the properties of the title compounds indicates that the strong CuCu coupling along the Cu+2 chains within the conducting stacks of Cu(tatbp)I and Cu(pc)I has a minimal contribution from direct near-neighbor interactions and arises primarily from long-range carrier-mediated interactions. Anomalous g-shifts observed at low temperatures for Cu(tatbp)I are found to be dependent on magnetic field.

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