Deactivation of laser excited CH3F in CH3F-X mixtures

Eric Weitz*, George Flynn

*Corresponding author for this work

Research output: Contribution to journalArticle

79 Scopus citations

Abstract

The vibrational relaxation of CH3F in mixtures of rare gases, O2, N2, H2, and D2 has been studied by means of laser induced fluorescence. The data can be interpreted qualitatively in terms of a combination of V→T/R energy transfer processes from both the ν3 and ν6 v=1 states of CH 3F. V→A processes seem to be dominant for heavy collision partners while V→T processes appear to dominate for light collision partners. The quantitative agreement between theory and experiment is also considered.

Original languageEnglish (US)
Pages (from-to)2679-2683
Number of pages5
JournalThe Journal of Chemical Physics
Volume58
Issue number7
DOIs
StatePublished - Jan 1 1973

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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