Decapitation of dihydroporphyrazinediol derivatives: Synthesis and X-ray structure of a novel seco-porphyrazine

Hanlin Nie, Charlotte L. Stern, Anthony G.M. Barrett*, Brian M. Hoffman

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

32 Scopus citations

Abstract

The dihydroporphyrazinediol 8, which was prepared by Linstead macrocyclisation of 2,5-diiminopyrrolidine with 3,4-bis(4-tert-butylphenyl)pyrroline-2,5-diimine, followed by TFA demetallation and OsO4 tetroxide mediated dihydroxylation, underwent reaction with Ni(OAc)2 at 100°C in the presence of air to give the novel seco-porphyrazine 10, the structure of which was established by an X-ray crystallographic study.

Original languageEnglish (US)
Pages (from-to)703-704
Number of pages2
JournalChemical Communications
Issue number8
DOIs
StatePublished - Apr 21 1999

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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