The dihydroporphyrazinediol 8, which was prepared by Linstead macrocyclisation of 2,5-diiminopyrrolidine with 3,4-bis(4-tert-butylphenyl)pyrroline-2,5-diimine, followed by TFA demetallation and OsO4 tetroxide mediated dihydroxylation, underwent reaction with Ni(OAc)2 at 100°C in the presence of air to give the novel seco-porphyrazine 10, the structure of which was established by an X-ray crystallographic study.
|Original language||English (US)|
|Number of pages||2|
|State||Published - Apr 21 1999|
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
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CCDC 118312: Experimental Crystal Structure Determination
Nie, H. (Creator), Stern, C. L. (Creator), Barrett, A. G. M. (Creator) & Hoffman, B. M. (Creator), Cambridge Crystallographic Data Centre, 1999
DOI: 10.5517/cc3z3jp, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc3z3jp&sid=DataCite