Decapitation of dihydroporphyrazinediol derivatives: Synthesis and X-ray structure of a novel seco-porphyrazine

Hanlin Nie; Charlotte L. Stern; Anthony G.M. Barrett; Brian M. Hoffman

doi:10.1039/a900555b

Decapitation of dihydroporphyrazinediol derivatives: Synthesis and X-ray structure of a novel seco-porphyrazine

Hanlin Nie, Charlotte L. Stern, Anthony G.M. Barrett^*, Brian M. Hoffman

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

The dihydroporphyrazinediol 8, which was prepared by Linstead macrocyclisation of 2,5-diiminopyrrolidine with 3,4-bis(4-tert-butylphenyl)pyrroline-2,5-diimine, followed by TFA demetallation and OsO₄ tetroxide mediated dihydroxylation, underwent reaction with Ni(OAc)₂ at 100°C in the presence of air to give the novel seco-porphyrazine 10, the structure of which was established by an X-ray crystallographic study.

Original language	English (US)
Pages (from-to)	703-704
Number of pages	2
Journal	Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/a900555b
State	Published - Apr 21 1999

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/a900555b

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title = "Decapitation of dihydroporphyrazinediol derivatives: Synthesis and X-ray structure of a novel seco-porphyrazine",

abstract = "The dihydroporphyrazinediol 8, which was prepared by Linstead macrocyclisation of 2,5-diiminopyrrolidine with 3,4-bis(4-tert-butylphenyl)pyrroline-2,5-diimine, followed by TFA demetallation and OsO4 tetroxide mediated dihydroxylation, underwent reaction with Ni(OAc)2 at 100°C in the presence of air to give the novel seco-porphyrazine 10, the structure of which was established by an X-ray crystallographic study.",

author = "Hanlin Nie and Stern, {Charlotte L.} and Barrett, {Anthony G.M.} and Hoffman, {Brian M.}",

year = "1999",

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doi = "10.1039/a900555b",

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pages = "703--704",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Decapitation of dihydroporphyrazinediol derivatives

T2 - Synthesis and X-ray structure of a novel seco-porphyrazine

AU - Nie, Hanlin

AU - Stern, Charlotte L.

AU - Barrett, Anthony G.M.

AU - Hoffman, Brian M.

PY - 1999/4/21

Y1 - 1999/4/21

N2 - The dihydroporphyrazinediol 8, which was prepared by Linstead macrocyclisation of 2,5-diiminopyrrolidine with 3,4-bis(4-tert-butylphenyl)pyrroline-2,5-diimine, followed by TFA demetallation and OsO4 tetroxide mediated dihydroxylation, underwent reaction with Ni(OAc)2 at 100°C in the presence of air to give the novel seco-porphyrazine 10, the structure of which was established by an X-ray crystallographic study.

AB - The dihydroporphyrazinediol 8, which was prepared by Linstead macrocyclisation of 2,5-diiminopyrrolidine with 3,4-bis(4-tert-butylphenyl)pyrroline-2,5-diimine, followed by TFA demetallation and OsO4 tetroxide mediated dihydroxylation, underwent reaction with Ni(OAc)2 at 100°C in the presence of air to give the novel seco-porphyrazine 10, the structure of which was established by an X-ray crystallographic study.

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Decapitation of dihydroporphyrazinediol derivatives: Synthesis and X-ray structure of a novel seco-porphyrazine

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CCDC 118312: Experimental Crystal Structure Determination

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Decapitation of dihydroporphyrazinediol derivatives: Synthesis and X-ray structure of a novel seco-porphyrazine

Abstract

ASJC Scopus subject areas

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CCDC 118312: Experimental Crystal Structure Determination

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