Delocalization Transition in Colloidal Crystals

Hector Lopez-Rios, Ali Ehlen, Monica Olvera De La Cruz*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

6 Scopus citations


Sublattice melting is the loss of order of one lattice component in binary or ternary ionic crystals upon increasing the temperature. A related transition has been predicted in colloidal crystals. To understand the nature of this transition, we study delocalization in self-assembled, size-asymmetric binary colloidal crystals using a generalized molecular dynamics model. Focusing on body-centered cubic (BCC) lattices, we observe a smooth change from localized-to-delocalized interstitial particles for a variety of interaction strengths. Thermodynamic arguments, mainly the absence of a discontinuity in the heat capacity, suggest that the passage from localization-to-delocalization is continuous and not a phase transition. This change is enhanced by lattice vibrations, and the temperature of the onset of delocalization can be tuned by the strength of the interaction between the colloid species. Therefore, the localized and delocalized regimes of the sublattice are dominated by enthalpic and entropic driving forces, respectively. This work sets the stage for future studies of sublattice melting in colloidal systems with different stoichiometries and lattice types and it provides insights into superionic materials, which have the potential for application in energy storage technologies.

Original languageEnglish (US)
Pages (from-to)1096-1106
Number of pages11
JournalJournal of Physical Chemistry C
Issue number1
StatePublished - Jan 14 2021

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films


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