TY - JOUR
T1 - Design in solid state synthesis based on phase homologies
T2 - A1-xSn9-xBi11+xSe26 (A=K, Rb, Cs) - A new member of the grand homologous series Am[M6Se8]m[M5+nSe 9+n] with M=Sn and Bi
AU - Mrotzek, Antje
AU - Kanatzidis, Mercouri G.
N1 - Funding Information:
Financial support from the Office of Naval Research and the Deutsche Forschungs-gemeinschaft is gratefully acknowledged.
PY - 2002/9
Y1 - 2002/9
N2 - Both the composition and structure of A1-xSn9-xBi11+xSe26 (A = K, Rb, Cs) were predicted on the basis of the homologous series Am[M6Se8]mlM5+nSe 9+n] (M=Sn, Bi) and targeted for synthesis. A1-xSn9-xBi11+xSe26 adopts a new structure type that fits the structural evolution of the homologous series.
AB - Both the composition and structure of A1-xSn9-xBi11+xSe26 (A = K, Rb, Cs) were predicted on the basis of the homologous series Am[M6Se8]mlM5+nSe 9+n] (M=Sn, Bi) and targeted for synthesis. A1-xSn9-xBi11+xSe26 adopts a new structure type that fits the structural evolution of the homologous series.
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U2 - 10.1016/S0022-4596(01)99482-4
DO - 10.1016/S0022-4596(01)99482-4
M3 - Article
AN - SCOPUS:0036736596
SN - 0022-4596
VL - 167
SP - 299
EP - 301
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
IS - 2
ER -