Design in solid state synthesis based on phase homologies: A1-xSn9-xBi11+xSe26 (A=K, Rb, Cs) - A new member of the grand homologous series Am[M6Se8]m[M5+nSe 9+n] with M=Sn and Bi

Antje Mrotzek; Mercouri G. Kanatzidis

doi:10.1016/S0022-4596(01)99482-4

Design in solid state synthesis based on phase homologies: A_1-xSn_9-xBi_11+xSe₂₆ (A=K, Rb, Cs) - A new member of the grand homologous series A_m[M₆Se₈]_m[M_5+nSe _9+n] with M=Sn and Bi

Antje Mrotzek, Mercouri G. Kanatzidis^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Both the composition and structure of A_1-xSn_9-xBi_11+xSe₂₆ (A = K, Rb, Cs) were predicted on the basis of the homologous series A_m[M₆Se₈]_mlM_5+nSe _9+n] (M=Sn, Bi) and targeted for synthesis. A_1-xSn_9-xBi_11+xSe₂₆ adopts a new structure type that fits the structural evolution of the homologous series.

Original language	English (US)
Pages (from-to)	299-301
Number of pages	3
Journal	Journal of Solid State Chemistry
Volume	167
Issue number	2
DOIs	https://doi.org/10.1016/S0022-4596(01)99482-4
State	Published - Sep 2002

Funding

Financial support from the Office of Naval Research and the Deutsche Forschungs-gemeinschaft is gratefully acknowledged.

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0022-4596(01)99482-4

Cite this

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title = "Design in solid state synthesis based on phase homologies: A1-xSn9-xBi11+xSe26 (A=K, Rb, Cs) - A new member of the grand homologous series Am[M6Se8]m[M5+nSe 9+n] with M=Sn and Bi",

abstract = "Both the composition and structure of A1-xSn9-xBi11+xSe26 (A = K, Rb, Cs) were predicted on the basis of the homologous series Am[M6Se8]mlM5+nSe 9+n] (M=Sn, Bi) and targeted for synthesis. A1-xSn9-xBi11+xSe26 adopts a new structure type that fits the structural evolution of the homologous series.",

author = "Antje Mrotzek and Kanatzidis, {Mercouri G.}",

note = "Funding Information: Financial support from the Office of Naval Research and the Deutsche Forschungs-gemeinschaft is gratefully acknowledged.",

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journal = "Journal of Solid State Chemistry",

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AU - Mrotzek, Antje

AU - Kanatzidis, Mercouri G.

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AB - Both the composition and structure of A1-xSn9-xBi11+xSe26 (A = K, Rb, Cs) were predicted on the basis of the homologous series Am[M6Se8]mlM5+nSe 9+n] (M=Sn, Bi) and targeted for synthesis. A1-xSn9-xBi11+xSe26 adopts a new structure type that fits the structural evolution of the homologous series.

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