Design in solid state synthesis based on phase homologies: A1-xSn9-xBi11+xSe26 (A=K, Rb, Cs) - A new member of the grand homologous series Am[M6Se8]m[M5+nSe 9+n] with M=Sn and Bi

Antje Mrotzek; Mercouri G. Kanatzidis

doi:10.1016/S0022-4596(01)99482-4

Design in solid state synthesis based on phase homologies: A_1-xSn_9-xBi_11+xSe₂₆ (A=K, Rb, Cs) - A new member of the grand homologous series A_m[M₆Se₈]_m[M_5+nSe _9+n] with M=Sn and Bi

Antje Mrotzek, Mercouri G. Kanatzidis^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Both the composition and structure of A_1-xSn_9-xBi_11+xSe₂₆ (A = K, Rb, Cs) were predicted on the basis of the homologous series A_m[M₆Se₈]_mlM_5+nSe _9+n] (M=Sn, Bi) and targeted for synthesis. A_1-xSn_9-xBi_11+xSe₂₆ adopts a new structure type that fits the structural evolution of the homologous series.

Original language	English (US)
Pages (from-to)	299-301
Number of pages	3
Journal	Journal of Solid State Chemistry
Volume	167
Issue number	2
DOIs	https://doi.org/10.1016/S0022-4596(01)99482-4
State	Published - Sep 2002

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "Design in solid state synthesis based on phase homologies: A1-xSn9-xBi11+xSe26 (A=K, Rb, Cs) - A new member of the grand homologous series Am[M6Se8]m[M5+nSe 9+n] with M=Sn and Bi",

abstract = "Both the composition and structure of A1-xSn9-xBi11+xSe26 (A = K, Rb, Cs) were predicted on the basis of the homologous series Am[M6Se8]mlM5+nSe 9+n] (M=Sn, Bi) and targeted for synthesis. A1-xSn9-xBi11+xSe26 adopts a new structure type that fits the structural evolution of the homologous series.",

author = "Antje Mrotzek and Kanatzidis, {Mercouri G.}",

note = "Funding Information: Financial support from the Office of Naval Research and the Deutsche Forschungs-gemeinschaft is gratefully acknowledged.",

year = "2002",

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doi = "10.1016/S0022-4596(01)99482-4",

language = "English (US)",

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journal = "Journal of Solid State Chemistry",

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AU - Mrotzek, Antje

AU - Kanatzidis, Mercouri G.

N1 - Funding Information: Financial support from the Office of Naval Research and the Deutsche Forschungs-gemeinschaft is gratefully acknowledged.

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AB - Both the composition and structure of A1-xSn9-xBi11+xSe26 (A = K, Rb, Cs) were predicted on the basis of the homologous series Am[M6Se8]mlM5+nSe 9+n] (M=Sn, Bi) and targeted for synthesis. A1-xSn9-xBi11+xSe26 adopts a new structure type that fits the structural evolution of the homologous series.

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