TY - JOUR
T1 - Design of S-Substituted Fluorinated Aryl Sulfonamide-Tagged (S-FAST) Anions to Enable New Solvate Ionic Liquids for Battery Applications
AU - Huang, Mingjun
AU - Feng, Shuting
AU - Zhang, Wenxu
AU - Lopez, Jeffrey
AU - Qiao, Bo
AU - Tatara, Ryoichi
AU - Giordano, Livia
AU - Shao-Horn, Yang
AU - Johnson, Jeremiah A.
N1 - Funding Information:
The authors acknowledge the Samsung Advanced Institute of Technology (SAIT) for funding this research. S.F. gratefully acknowledges the Link Foundation for the Link Energy Fellowship. This research used the Extreme Science and Engineering Discovery Environment (XSEDE), which is supported by National Science Foundation Grant ACI-1548562. J.L. gratefully acknowledges support by an appointment to the Intelligence Community Postdoctoral Research Fellowship Program at the Massachusetts Institute of Technology, administered by the Oak Ridge Institute for Science and Education through an interagency agreement between the U.S. Department of Energy and the Office of the Director of National Intelligence.
Publisher Copyright:
© 2019 American Chemical Society.
PY - 2019/9/24
Y1 - 2019/9/24
N2 - Electrolytes with improved thermal and oxidative stability must be developed to achieve greater power and energy densities without compromising safety in modern energy storage devices. Because of their much-reduced solvent vapor pressure and expanded electrochemical windows, solvate ionic liquids (SILs) of lithium salts have recently attracted significant attention in this regard. The current palette of SILs is, however, limited to only a few suitable anions with limited chemical functionality. Guided by fundamental physical organic chemistry principles, we designed a new family of S-substituted fluorinated aryl sulfonamide-tagged anions that feature variable numbers of electronically neutral or withdrawing sulfide, sulfoxide, and sulfone substituents. Several salts of these electron deficient anions display very high electrochemical oxidative stability, good solubility, and a weakly coordinating nature that enables the synthesis of Li-based SILs with high thermal and electrochemical oxidative stability. This new family of functional, noncoordinating anions will potentially expand the scope of applications of SILs as safe electrolytes in battery devices.
AB - Electrolytes with improved thermal and oxidative stability must be developed to achieve greater power and energy densities without compromising safety in modern energy storage devices. Because of their much-reduced solvent vapor pressure and expanded electrochemical windows, solvate ionic liquids (SILs) of lithium salts have recently attracted significant attention in this regard. The current palette of SILs is, however, limited to only a few suitable anions with limited chemical functionality. Guided by fundamental physical organic chemistry principles, we designed a new family of S-substituted fluorinated aryl sulfonamide-tagged anions that feature variable numbers of electronically neutral or withdrawing sulfide, sulfoxide, and sulfone substituents. Several salts of these electron deficient anions display very high electrochemical oxidative stability, good solubility, and a weakly coordinating nature that enables the synthesis of Li-based SILs with high thermal and electrochemical oxidative stability. This new family of functional, noncoordinating anions will potentially expand the scope of applications of SILs as safe electrolytes in battery devices.
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U2 - 10.1021/acs.chemmater.9b02353
DO - 10.1021/acs.chemmater.9b02353
M3 - Article
AN - SCOPUS:85072317546
VL - 31
SP - 7558
EP - 7564
JO - Chemistry of Materials
JF - Chemistry of Materials
SN - 0897-4756
IS - 18
ER -