Design, synthesis, characterization, and catalytic properties of a large-pore metal-organic framework possessing single-site vanadyl(monocatecholate) moieties

Huong Giang T. Nguyen; Mitchell H. Weston; Amy A. Sarjeant; Daniel M. Gardner; Zhi An; Raanan Carmieli; Michael R. Wasielewski; Omar K. Farha; Joseph T. Hupp; Sonbinh T. Nguyen

doi:10.1021/cg400500t

Design, synthesis, characterization, and catalytic properties of a large-pore metal-organic framework possessing single-site vanadyl(monocatecholate) moieties

Huong Giang T. Nguyen, Mitchell H. Weston, Amy A. Sarjeant, Daniel M. Gardner, Zhi An, Raanan Carmieli, Michael R. Wasielewski, Omar K. Farha^*, Joseph T. Hupp, Sonbinh T. Nguyen

^*Corresponding author for this work

Chemistry

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42 Scopus citations

Abstract

Through a combination of protecting groups, postsynthesis deprotection, and postsynthesis metallation, a homogeneously inaccessible, single-site vanadyl(monocatecholate) moiety can be incorporated into the dipyridyl struts of a Zn-based, pillared paddlewheel MOF. The resulting MOF, which has large pores, exhibits catalytic activity in the benzylic oxidation of tetralin in the presence of tert-butylhydroperoxide.

Original language	English (US)
Pages (from-to)	3528-3534
Number of pages	7
Journal	Crystal Growth and Design
Volume	13
Issue number	8
DOIs	https://doi.org/10.1021/cg400500t
State	Published - Aug 7 2013

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1021/cg400500t

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Nguyen, H. G. T., Weston, M. H., Sarjeant, A. A., Gardner, D. M., An, Z., Carmieli, R., Wasielewski, M. R., Farha, O. K., Hupp, J. T., & Nguyen, S. T. (2013). Design, synthesis, characterization, and catalytic properties of a large-pore metal-organic framework possessing single-site vanadyl(monocatecholate) moieties. Crystal Growth and Design, 13(8), 3528-3534. https://doi.org/10.1021/cg400500t

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title = "Design, synthesis, characterization, and catalytic properties of a large-pore metal-organic framework possessing single-site vanadyl(monocatecholate) moieties",

abstract = "Through a combination of protecting groups, postsynthesis deprotection, and postsynthesis metallation, a homogeneously inaccessible, single-site vanadyl(monocatecholate) moiety can be incorporated into the dipyridyl struts of a Zn-based, pillared paddlewheel MOF. The resulting MOF, which has large pores, exhibits catalytic activity in the benzylic oxidation of tetralin in the presence of tert-butylhydroperoxide.",

author = "Nguyen, {Huong Giang T.} and Weston, {Mitchell H.} and Sarjeant, {Amy A.} and Gardner, {Daniel M.} and Zhi An and Raanan Carmieli and Wasielewski, {Michael R.} and Farha, {Omar K.} and Hupp, {Joseph T.} and Nguyen, {Sonbinh T.}",

year = "2013",

month = aug,

day = "7",

doi = "10.1021/cg400500t",

language = "English (US)",

volume = "13",

pages = "3528--3534",

journal = "Crystal Growth and Design",

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publisher = "American Chemical Society",

number = "8",

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Nguyen, HGT, Weston, MH, Sarjeant, AA, Gardner, DM, An, Z, Carmieli, R, Wasielewski, MR , Farha, OK , Hupp, JT & Nguyen, ST 2013, 'Design, synthesis, characterization, and catalytic properties of a large-pore metal-organic framework possessing single-site vanadyl(monocatecholate) moieties', Crystal Growth and Design, vol. 13, no. 8, pp. 3528-3534. https://doi.org/10.1021/cg400500t

Design, synthesis, characterization, and catalytic properties of a large-pore metal-organic framework possessing single-site vanadyl(monocatecholate) moieties. / Nguyen, Huong Giang T.; Weston, Mitchell H.; Sarjeant, Amy A. et al.
In: Crystal Growth and Design, Vol. 13, No. 8, 07.08.2013, p. 3528-3534.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Design, synthesis, characterization, and catalytic properties of a large-pore metal-organic framework possessing single-site vanadyl(monocatecholate) moieties

AU - Nguyen, Huong Giang T.

AU - Weston, Mitchell H.

AU - Sarjeant, Amy A.

AU - Gardner, Daniel M.

AU - An, Zhi

AU - Carmieli, Raanan

AU - Wasielewski, Michael R.

AU - Farha, Omar K.

AU - Hupp, Joseph T.

AU - Nguyen, Sonbinh T.

PY - 2013/8/7

Y1 - 2013/8/7

N2 - Through a combination of protecting groups, postsynthesis deprotection, and postsynthesis metallation, a homogeneously inaccessible, single-site vanadyl(monocatecholate) moiety can be incorporated into the dipyridyl struts of a Zn-based, pillared paddlewheel MOF. The resulting MOF, which has large pores, exhibits catalytic activity in the benzylic oxidation of tetralin in the presence of tert-butylhydroperoxide.

AB - Through a combination of protecting groups, postsynthesis deprotection, and postsynthesis metallation, a homogeneously inaccessible, single-site vanadyl(monocatecholate) moiety can be incorporated into the dipyridyl struts of a Zn-based, pillared paddlewheel MOF. The resulting MOF, which has large pores, exhibits catalytic activity in the benzylic oxidation of tetralin in the presence of tert-butylhydroperoxide.

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IS - 8

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Design, synthesis, characterization, and catalytic properties of a large-pore metal-organic framework possessing single-site vanadyl(monocatecholate) moieties

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CCDC 960412: Experimental Crystal Structure Determination

CCDC 960413: Experimental Crystal Structure Determination

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Design, synthesis, characterization, and catalytic properties of a large-pore metal-organic framework possessing single-site vanadyl(monocatecholate) moieties

Abstract

ASJC Scopus subject areas

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CCDC 960412: Experimental Crystal Structure Determination

CCDC 960413: Experimental Crystal Structure Determination

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