Designing higher surface area metal-organic frameworks: Are triple bonds better than phenyls?

Omar K. Farha; Christopher E. Wilmer; Ibrahim Eryazici; Brad G. Hauser; Philip A. Parilla; Kevin ONeill; Amy A. Sarjeant; Sonbinh T. Nguyen; Randall Q. Snurr; Joseph T. Hupp

doi:10.1021/ja302623w

Designing higher surface area metal-organic frameworks: Are triple bonds better than phenyls?

Omar K. Farha^*, Christopher E. Wilmer, Ibrahim Eryazici, Brad G. Hauser, Philip A. Parilla, Kevin ONeill, Amy A. Sarjeant, Sonbinh T. Nguyen, Randall Q. Snurr, Joseph T. Hupp

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

178 Scopus citations

Abstract

We have synthesized, characterized, and computationally validated the high Brunauer-Emmett-Teller surface area and hydrogen uptake of a new, noncatenating metal-organic framework (MOF) material, NU-111. Our results imply that replacing the phenyl spacers of organic linkers with triple-bond spacers is an effective strategy for boosting molecule-accessible gravimetric surface areas of MOFs and related high-porosity materials.

Original language	English (US)
Pages (from-to)	9860-9863
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	24
DOIs	https://doi.org/10.1021/ja302623w
State	Published - Jun 20 2012

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja302623w

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title = "Designing higher surface area metal-organic frameworks: Are triple bonds better than phenyls?",

abstract = "We have synthesized, characterized, and computationally validated the high Brunauer-Emmett-Teller surface area and hydrogen uptake of a new, noncatenating metal-organic framework (MOF) material, NU-111. Our results imply that replacing the phenyl spacers of organic linkers with triple-bond spacers is an effective strategy for boosting molecule-accessible gravimetric surface areas of MOFs and related high-porosity materials.",

author = "Farha, {Omar K.} and Wilmer, {Christopher E.} and Ibrahim Eryazici and Hauser, {Brad G.} and Parilla, {Philip A.} and Kevin ONeill and Sarjeant, {Amy A.} and Nguyen, {Sonbinh T.} and Snurr, {Randall Q.} and Hupp, {Joseph T.}",

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T1 - Designing higher surface area metal-organic frameworks

T2 - Are triple bonds better than phenyls?

AU - Farha, Omar K.

AU - Wilmer, Christopher E.

AU - Eryazici, Ibrahim

AU - Hauser, Brad G.

AU - Parilla, Philip A.

AU - ONeill, Kevin

AU - Sarjeant, Amy A.

AU - Nguyen, Sonbinh T.

AU - Snurr, Randall Q.

AU - Hupp, Joseph T.

PY - 2012/6/20

Y1 - 2012/6/20

N2 - We have synthesized, characterized, and computationally validated the high Brunauer-Emmett-Teller surface area and hydrogen uptake of a new, noncatenating metal-organic framework (MOF) material, NU-111. Our results imply that replacing the phenyl spacers of organic linkers with triple-bond spacers is an effective strategy for boosting molecule-accessible gravimetric surface areas of MOFs and related high-porosity materials.

AB - We have synthesized, characterized, and computationally validated the high Brunauer-Emmett-Teller surface area and hydrogen uptake of a new, noncatenating metal-organic framework (MOF) material, NU-111. Our results imply that replacing the phenyl spacers of organic linkers with triple-bond spacers is an effective strategy for boosting molecule-accessible gravimetric surface areas of MOFs and related high-porosity materials.

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DO - 10.1021/ja302623w

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

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ER -

Designing higher surface area metal-organic frameworks: Are triple bonds better than phenyls?

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CCDC 898090: Experimental Crystal Structure Determination

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Designing higher surface area metal-organic frameworks: Are triple bonds better than phenyls?

Abstract

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Datasets

CCDC 898090: Experimental Crystal Structure Determination

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