Designing higher surface area metal-organic frameworks: Are triple bonds better than phenyls?

Omar k Farha*, Christopher E. Wilmer, Ibrahim Eryazici, Brad G. Hauser, Philip A. Parilla, Kevin ONeill, Amy A. Sarjeant, SonBinh Nguyen, Randall Q Snurr, Joseph T Hupp

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

152 Scopus citations

Abstract

We have synthesized, characterized, and computationally validated the high Brunauer-Emmett-Teller surface area and hydrogen uptake of a new, noncatenating metal-organic framework (MOF) material, NU-111. Our results imply that replacing the phenyl spacers of organic linkers with triple-bond spacers is an effective strategy for boosting molecule-accessible gravimetric surface areas of MOFs and related high-porosity materials.

Original languageEnglish (US)
Pages (from-to)9860-9863
Number of pages4
JournalJournal of the American Chemical Society
Volume134
Issue number24
DOIs
StatePublished - Jun 20 2012

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

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