Designing surface-confined coordination oligomers

Marc Altman, Meital Rachamim, Takahiko Ichiki, Mark A. Iron, Guennadi Evmenenko, Pulak Dutta, Milko E. Van Der Boom

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

(Figure Presented) Designer materials: HOMO-LUMO engineering of coordination-based oligomers covalently bound to silicon or glass has been achieved by the use of a partially fluorinated chromophore (see graphic). The experimental and computationally derived physical chemical properties of these assemblies are compared to their non-fluorinated analogues.

Original languageEnglish (US)
Pages (from-to)6744-6747
Number of pages4
JournalChemistry - A European Journal
Volume16
Issue number23
DOIs
StatePublished - Jun 18 2010

Keywords

  • Coordination polymers
  • Density functional calculations
  • HOMO-LUMO engineering
  • Oligomers
  • Solid-state structures

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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