Di-μ-acetone-κ2O:O-bis[(acetone-κO) -aqualithium(I)] di-μ-acetone-κ2O:O-bis-[diaqualithium(I)] tetrakis{[phthalocyan-inato(2-)-κ4N,N′,N″, N‴]lithiate(I)}

David A. Grossie; William A. Feld; Lawrence Scanlon; Giselle Sandi; Zdzislaw Wawrzak

doi:10.1107/S1600536806008488

Di-μ-acetone-κ²O:O-bis[(acetone-κO) -aqualithium(I)] di-μ-acetone-κ²O:O-bis-[diaqualithium(I)] tetrakis{[phthalocyan-inato(2-)-κ⁴N,N′,N″, N‴]lithiate(I)}

David A. Grossie^*, William A. Feld, Lawrence Scanlon, Giselle Sandi, Zdzislaw Wawrzak

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The crystals of the title compound, [Li₂(C₃H ₆O)₄(H₂O)₂]-[Li₂(C ₃H₆O)₂(H₂O)₄] [Li(C ₃₂H₁₆N₈)]₄, were obtained by a recrystallization of dilithium phthalocyanine from an acetone/water/toluene solution. The title structure consists of two independent Li-phthalocyanine complexes along with acetone-bridged lithium dimers. The lithium dimers are located on inversion centers. The crystal structure is stabilized by a network of hydrogen bonds.

Original language	English (US)
Pages (from-to)	m827-m829
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	4
DOIs	https://doi.org/10.1107/S1600536806008488
State	Published - Apr 1 2006

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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@article{585eb167594c4ae1bd5fac654b45c8cf,

title = "Di-μ-acetone-κ2O:O-bis[(acetone-κO) -aqualithium(I)] di-μ-acetone-κ2O:O-bis-[diaqualithium(I)] tetrakis{[phthalocyan-inato(2-)-κ4N,N′,N″, N‴]lithiate(I)}",

abstract = "The crystals of the title compound, [Li2(C3H 6O)4(H2O)2]-[Li2(C 3H6O)2(H2O)4] [Li(C 32H16N8)]4, were obtained by a recrystallization of dilithium phthalocyanine from an acetone/water/toluene solution. The title structure consists of two independent Li-phthalocyanine complexes along with acetone-bridged lithium dimers. The lithium dimers are located on inversion centers. The crystal structure is stabilized by a network of hydrogen bonds.",

author = "Grossie, {David A.} and Feld, {William A.} and Lawrence Scanlon and Giselle Sandi and Zdzislaw Wawrzak",

year = "2006",

month = apr,

day = "1",

doi = "10.1107/S1600536806008488",

language = "English (US)",

volume = "62",

pages = "m827--m829",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "4",

}

Di-μ-acetone-κ²O:O-bis[(acetone-κO) -aqualithium(I)] di-μ-acetone-κ²O:O-bis-[diaqualithium(I)] tetrakis{[phthalocyan-inato(2-)-κ⁴N,N′,N″, N‴]lithiate(I)}. / Grossie, David A.; Feld, William A.; Scanlon, Lawrence et al.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 62, No. 4, 01.04.2006, p. m827-m829.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Di-μ-acetone-κ2O:O-bis[(acetone-κO) -aqualithium(I)] di-μ-acetone-κ2O:O-bis-[diaqualithium(I)] tetrakis{[phthalocyan-inato(2-)-κ4N,N′,N″, N‴]lithiate(I)}

AU - Grossie, David A.

AU - Feld, William A.

AU - Scanlon, Lawrence

AU - Sandi, Giselle

AU - Wawrzak, Zdzislaw

PY - 2006/4/1

Y1 - 2006/4/1

N2 - The crystals of the title compound, [Li2(C3H 6O)4(H2O)2]-[Li2(C 3H6O)2(H2O)4] [Li(C 32H16N8)]4, were obtained by a recrystallization of dilithium phthalocyanine from an acetone/water/toluene solution. The title structure consists of two independent Li-phthalocyanine complexes along with acetone-bridged lithium dimers. The lithium dimers are located on inversion centers. The crystal structure is stabilized by a network of hydrogen bonds.

AB - The crystals of the title compound, [Li2(C3H 6O)4(H2O)2]-[Li2(C 3H6O)2(H2O)4] [Li(C 32H16N8)]4, were obtained by a recrystallization of dilithium phthalocyanine from an acetone/water/toluene solution. The title structure consists of two independent Li-phthalocyanine complexes along with acetone-bridged lithium dimers. The lithium dimers are located on inversion centers. The crystal structure is stabilized by a network of hydrogen bonds.

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U2 - 10.1107/S1600536806008488

DO - 10.1107/S1600536806008488

M3 - Article

AN - SCOPUS:33744928369

SN - 1600-5368

VL - 62

SP - m827-m829

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

Di-μ-acetone-κ²O:O-bis[(acetone-κO) -aqualithium(I)] di-μ-acetone-κ²O:O-bis-[diaqualithium(I)] tetrakis{[phthalocyan-inato(2-)-κ⁴N,N′,N″, N‴]lithiate(I)}

Abstract

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