Diamminebis(1,5‐cyclooctadiene)(μ‐1,4,10,13‐tetraoxa‐7, 16‐diazacyclooctadecane‐N7, N16)dirhodiumbis‐(hexafluorophosphate): An Example of Simultaneous First and Second Sphere Coordination

Howard M. Colquhoun; Simon M. Doughty; Alexandra M Z Slawin; J. Fraser Stoddart; David J. Williams

doi:10.1002/anie.198501351

Diamminebis(1,5‐cyclooctadiene)(μ‐1,4,10,13‐tetraoxa‐7, 16‐diazacyclooctadecane‐N⁷, N¹⁶)dirhodiumbis‐(hexafluorophosphate): An Example of Simultaneous First and Second Sphere Coordination

Howard M. Colquhoun, Simon M. Doughty, Alexandra M Z Slawin, J. Fraser Stoddart^*, David J. Williams

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article

21 Scopus citations

Abstract

The first example of a nitrogen‐containing crown ether acting as both a first and second sphere ligand towards a transition metal is found in the rhodium complex 1. This complex contains a crystallographic center of symmetry and is stabilized by intramolecular hydrogen bridges. (Formula Presented.)

Original language	English (US)
Pages (from-to)	135-136
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	24
Issue number	2
DOIs	https://doi.org/10.1002/anie.198501351
State	Published - Jan 1 1985

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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Colquhoun, H. M., Doughty, S. M., Slawin, A. M. Z., Stoddart, J. F., & Williams, D. J. (1985). Diamminebis(1,5‐cyclooctadiene)(μ‐1,4,10,13‐tetraoxa‐7, 16‐diazacyclooctadecane‐N⁷, N¹⁶)dirhodiumbis‐(hexafluorophosphate): An Example of Simultaneous First and Second Sphere Coordination. Angewandte Chemie International Edition in English, 24(2), 135-136. https://doi.org/10.1002/anie.198501351

Colquhoun, Howard M. ; Doughty, Simon M. ; Slawin, Alexandra M Z ; Stoddart, J. Fraser ; Williams, David J. / Diamminebis(1,5‐cyclooctadiene)(μ‐1,4,10,13‐tetraoxa‐7, 16‐diazacyclooctadecane‐N⁷, N¹⁶)dirhodiumbis‐(hexafluorophosphate) : An Example of Simultaneous First and Second Sphere Coordination. In: Angewandte Chemie International Edition in English. 1985 ; Vol. 24, No. 2. pp. 135-136.

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title = "Diamminebis(1,5‐cyclooctadiene)(μ‐1,4,10,13‐tetraoxa‐7, 16‐diazacyclooctadecane‐N7, N16)dirhodiumbis‐(hexafluorophosphate): An Example of Simultaneous First and Second Sphere Coordination",

abstract = "The first example of a nitrogen‐containing crown ether acting as both a first and second sphere ligand towards a transition metal is found in the rhodium complex 1. This complex contains a crystallographic center of symmetry and is stabilized by intramolecular hydrogen bridges. (Formula Presented.)",

author = "Colquhoun, {Howard M.} and Doughty, {Simon M.} and Slawin, {Alexandra M Z} and Stoddart, {J. Fraser} and Williams, {David J.}",

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doi = "10.1002/anie.198501351",

language = "English (US)",

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pages = "135--136",

journal = "Angewandte Chemie - International Edition",

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Colquhoun, HM, Doughty, SM, Slawin, AMZ, Stoddart, JF & Williams, DJ 1985, 'Diamminebis(1,5‐cyclooctadiene)(μ‐1,4,10,13‐tetraoxa‐7, 16‐diazacyclooctadecane‐N⁷, N¹⁶)dirhodiumbis‐(hexafluorophosphate): An Example of Simultaneous First and Second Sphere Coordination', Angewandte Chemie International Edition in English, vol. 24, no. 2, pp. 135-136. https://doi.org/10.1002/anie.198501351

Diamminebis(1,5‐cyclooctadiene)(μ‐1,4,10,13‐tetraoxa‐7, 16‐diazacyclooctadecane‐N⁷, N¹⁶)dirhodiumbis‐(hexafluorophosphate) : An Example of Simultaneous First and Second Sphere Coordination. / Colquhoun, Howard M.; Doughty, Simon M.; Slawin, Alexandra M Z; Stoddart, J. Fraser; Williams, David J.

In: Angewandte Chemie International Edition in English, Vol. 24, No. 2, 01.01.1985, p. 135-136.

Research output: Contribution to journal › Article

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T2 - An Example of Simultaneous First and Second Sphere Coordination

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Colquhoun HM, Doughty SM, Slawin AMZ, Stoddart JF, Williams DJ. Diamminebis(1,5‐cyclooctadiene)(μ‐1,4,10,13‐tetraoxa‐7, 16‐diazacyclooctadecane‐N⁷, N¹⁶)dirhodiumbis‐(hexafluorophosphate): An Example of Simultaneous First and Second Sphere Coordination. Angewandte Chemie International Edition in English. 1985 Jan 1;24(2):135-136. https://doi.org/10.1002/anie.198501351