Diene Synthesis by the Reductive Transposition of 1,2-Allenols

Vincent J. Rinaolo*, Emily E. Robinson, Abdallah B. Diagne, Scott E. Schaus, Regan J. Thomson

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Monoalkyl diazene species are versatile intermediates that have enabled many useful synthetic transformations in complex chemical environments. Herein we report the reductive transposition of 1,2-allenols for the direct synthesis of dienes through an alkene walk process.

Original languageEnglish (US)
Pages (from-to)2073-2076
Number of pages4
JournalSynlett
Volume30
Issue number18
DOIs
StatePublished - Jan 1 2019

Keywords

  • allenol
  • diazene
  • diene
  • reduction
  • transposition

ASJC Scopus subject areas

  • Organic Chemistry

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