Directed self-assembly of a ring-in-ring complex

Ross S. Forgan; Douglas C. Friedman; Charlotte L. Stern; Carson J. Bruns; J. Fraser Stoddart

doi:10.1039/c0cc00776e

Directed self-assembly of a ring-in-ring complex

Ross S. Forgan, Douglas C. Friedman, Charlotte L. Stern, Carson J. Bruns, J. Fraser Stoddart

Chemistry

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

A strategic modification to the corner ligands in Pd^II- containing, electron-poor cyclophanes has profound repercussions for their assemblies with electron-rich aromatic crown ethers in both the solid and solution states; the formation of ring-in-ring complexes can override competing [3]catenane production on masking the hydrogen bond donor capabilities of the corner ligands.

Original language	English (US)
Pages (from-to)	5861-5863
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	32
DOIs	https://doi.org/10.1039/c0cc00776e
State	Published - Aug 28 2010

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "A strategic modification to the corner ligands in PdII- containing, electron-poor cyclophanes has profound repercussions for their assemblies with electron-rich aromatic crown ethers in both the solid and solution states; the formation of ring-in-ring complexes can override competing [3]catenane production on masking the hydrogen bond donor capabilities of the corner ligands.",

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