Dirubidium tetrathiotungstate, Rb2[WS4]

Jiyong Yao; James A. Ibers

doi:10.1107/S1600536804000169

Dirubidium tetrathiotungstate, Rb₂[WS₄]

Jiyong Yao, James A. Ibers^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

Rb₂[WS₄] crystallizes in the orthorhombic space group Pnma and is isostructural with Cs₂[MoS₄], Rb ₂[MoS₄], K₂[MoS₄] and (NH ₄)₂[WS₄]. The structure contains discrete tetrahedral [WS₄]^2- anions of symmetry m, separated by Rb⁺ cations. One of the two unique Rb⁺ cations is surrounded by nine S atoms and the other by ten S atoms.

Original language	English (US)
Pages (from-to)	i10-i11
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	2
DOIs	https://doi.org/10.1107/S1600536804000169
State	Published - Feb 1 2004

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Dirubidium tetrathiotungstate, Rb2[WS4]",

abstract = "Rb2[WS4] crystallizes in the orthorhombic space group Pnma and is isostructural with Cs2[MoS4], Rb 2[MoS4], K2[MoS4] and (NH 4)2[WS4]. The structure contains discrete tetrahedral [WS4]2- anions of symmetry m, separated by Rb+ cations. One of the two unique Rb+ cations is surrounded by nine S atoms and the other by ten S atoms.",

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AU - Ibers, James A.

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N2 - Rb2[WS4] crystallizes in the orthorhombic space group Pnma and is isostructural with Cs2[MoS4], Rb 2[MoS4], K2[MoS4] and (NH 4)2[WS4]. The structure contains discrete tetrahedral [WS4]2- anions of symmetry m, separated by Rb+ cations. One of the two unique Rb+ cations is surrounded by nine S atoms and the other by ten S atoms.

AB - Rb2[WS4] crystallizes in the orthorhombic space group Pnma and is isostructural with Cs2[MoS4], Rb 2[MoS4], K2[MoS4] and (NH 4)2[WS4]. The structure contains discrete tetrahedral [WS4]2- anions of symmetry m, separated by Rb+ cations. One of the two unique Rb+ cations is surrounded by nine S atoms and the other by ten S atoms.

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Dirubidium tetrathiotungstate, Rb₂[WS₄]

Abstract

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