Distannoxane speciation during esterification catalysis: Revealing insights provided by electrospray ionization mass spectrometry

Evan Crawford; Tracy Lohr; Erin M. Leitao; Samantha Kwok; J. Scott McIndoe

doi:10.1039/b913492a

Distannoxane speciation during esterification catalysis: Revealing insights provided by electrospray ionization mass spectrometry

Evan Crawford, Tracy Lohr, Erin M. Leitao, Samantha Kwok, J. Scott McIndoe

Chemistry

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Dimeric tetraalkyldistannoxanes are have been reported to catalyze esterification reactions, but are difficult to investigate in detail due to the lack of suitable spectroscopic handles. Electrospray ionization mass spectrometry (ESI-MS), in conjunction with a tethered charge on a tin atom, reveals that immediate decomposition to mono-tin carboxylate compounds occurs in the presence of carboxylic acid.

Original language	English (US)
Pages (from-to)	9110-9112
Number of pages	3
Journal	Dalton Transactions
Issue number	42
DOIs	https://doi.org/10.1039/b913492a
State	Published - Oct 27 2009

ASJC Scopus subject areas

Inorganic Chemistry

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abstract = "Dimeric tetraalkyldistannoxanes are have been reported to catalyze esterification reactions, but are difficult to investigate in detail due to the lack of suitable spectroscopic handles. Electrospray ionization mass spectrometry (ESI-MS), in conjunction with a tethered charge on a tin atom, reveals that immediate decomposition to mono-tin carboxylate compounds occurs in the presence of carboxylic acid.",

author = "Evan Crawford and Tracy Lohr and Leitao, {Erin M.} and Samantha Kwok and McIndoe, {J. Scott}",

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AU - Crawford, Evan

AU - Lohr, Tracy

AU - Leitao, Erin M.

AU - Kwok, Samantha

AU - McIndoe, J. Scott

PY - 2009/10/27

Y1 - 2009/10/27

N2 - Dimeric tetraalkyldistannoxanes are have been reported to catalyze esterification reactions, but are difficult to investigate in detail due to the lack of suitable spectroscopic handles. Electrospray ionization mass spectrometry (ESI-MS), in conjunction with a tethered charge on a tin atom, reveals that immediate decomposition to mono-tin carboxylate compounds occurs in the presence of carboxylic acid.

AB - Dimeric tetraalkyldistannoxanes are have been reported to catalyze esterification reactions, but are difficult to investigate in detail due to the lack of suitable spectroscopic handles. Electrospray ionization mass spectrometry (ESI-MS), in conjunction with a tethered charge on a tin atom, reveals that immediate decomposition to mono-tin carboxylate compounds occurs in the presence of carboxylic acid.

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Distannoxane speciation during esterification catalysis: Revealing insights provided by electrospray ionization mass spectrometry

Abstract

ASJC Scopus subject areas

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