Dithiocarbamate-Functionalized Dendrimers as Ligands for Metal Complexes

Quentin J. McCubbin, Fiona J. Stoddart, Thomas Welton*, Andrew J P White, David J. Williams

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

31 Scopus citations

Abstract

Zeroth- and first-generation poly(amido)amine dendrimers have been functionalized with dithiocarbamate end groups and reacted with ruthenium complexes, to form metallodendrimers. Monomeric ruthenium dithiocarbamate complexes were also prepared as model compounds and their spectroscopic data compared with those of the metallodendrimers. The novel compounds were characterized using NMR spectroscopy (1H and 13C) and mass spectrometry. The compound [Ru(S2CNMe2)(PPh3)(η5-C 5H5)] has also been characterized crystallographically.

Original languageEnglish (US)
Pages (from-to)3753-3758
Number of pages6
JournalInorganic Chemistry
Volume37
Issue number15
StatePublished - Jul 27 1998

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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