Dithiocarbamate-Functionalized Dendrimers as Ligands for Metal Complexes

Quentin J. McCubbin; Fiona J. Stoddart; Thomas Welton; Andrew J P White; David J. Williams

doi:10.1021/ic980067b

Dithiocarbamate-Functionalized Dendrimers as Ligands for Metal Complexes

Quentin J. McCubbin, Fiona J. Stoddart, Thomas Welton^*, Andrew J P White, David J. Williams

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

Zeroth- and first-generation poly(amido)amine dendrimers have been functionalized with dithiocarbamate end groups and reacted with ruthenium complexes, to form metallodendrimers. Monomeric ruthenium dithiocarbamate complexes were also prepared as model compounds and their spectroscopic data compared with those of the metallodendrimers. The novel compounds were characterized using NMR spectroscopy (¹H and ¹³C) and mass spectrometry. The compound [Ru(S₂CNMe₂)(PPh₃)(η⁵-C ₅H₅)] has also been characterized crystallographically.

Original language	English (US)
Pages (from-to)	3753-3758
Number of pages	6
Journal	Inorganic chemistry
Volume	37
Issue number	15
DOIs	https://doi.org/10.1021/ic980067b
State	Published - Jul 27 1998

ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry

Access to Document

10.1021/ic980067b

Cite this

@article{37305ad4d43d428fb140f917e45974c1,

title = "Dithiocarbamate-Functionalized Dendrimers as Ligands for Metal Complexes",

abstract = "Zeroth- and first-generation poly(amido)amine dendrimers have been functionalized with dithiocarbamate end groups and reacted with ruthenium complexes, to form metallodendrimers. Monomeric ruthenium dithiocarbamate complexes were also prepared as model compounds and their spectroscopic data compared with those of the metallodendrimers. The novel compounds were characterized using NMR spectroscopy (1H and 13C) and mass spectrometry. The compound [Ru(S2CNMe2)(PPh3)(η5-C 5H5)] has also been characterized crystallographically.",

author = "McCubbin, \{Quentin J.\} and Stoddart, \{Fiona J.\} and Thomas Welton and White, \{Andrew J P\} and Williams, \{David J.\}",

year = "1998",

month = jul,

day = "27",

doi = "10.1021/ic980067b",

language = "English (US)",

volume = "37",

pages = "3753--3758",

journal = "Inorganic chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "15",

}

TY - JOUR

T1 - Dithiocarbamate-Functionalized Dendrimers as Ligands for Metal Complexes

AU - McCubbin, Quentin J.

AU - Stoddart, Fiona J.

AU - Welton, Thomas

AU - White, Andrew J P

AU - Williams, David J.

PY - 1998/7/27

Y1 - 1998/7/27

N2 - Zeroth- and first-generation poly(amido)amine dendrimers have been functionalized with dithiocarbamate end groups and reacted with ruthenium complexes, to form metallodendrimers. Monomeric ruthenium dithiocarbamate complexes were also prepared as model compounds and their spectroscopic data compared with those of the metallodendrimers. The novel compounds were characterized using NMR spectroscopy (1H and 13C) and mass spectrometry. The compound [Ru(S2CNMe2)(PPh3)(η5-C 5H5)] has also been characterized crystallographically.

AB - Zeroth- and first-generation poly(amido)amine dendrimers have been functionalized with dithiocarbamate end groups and reacted with ruthenium complexes, to form metallodendrimers. Monomeric ruthenium dithiocarbamate complexes were also prepared as model compounds and their spectroscopic data compared with those of the metallodendrimers. The novel compounds were characterized using NMR spectroscopy (1H and 13C) and mass spectrometry. The compound [Ru(S2CNMe2)(PPh3)(η5-C 5H5)] has also been characterized crystallographically.

UR - http://www.scopus.com/inward/record.url?scp=0000782838&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000782838&partnerID=8YFLogxK

U2 - 10.1021/ic980067b

DO - 10.1021/ic980067b

M3 - Article

C2 - 11670475

AN - SCOPUS:0000782838

SN - 0020-1669

VL - 37

SP - 3753

EP - 3758

JO - Inorganic chemistry

JF - Inorganic chemistry

IS - 15

ER -

Dithiocarbamate-Functionalized Dendrimers as Ligands for Metal Complexes

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this