Dithiocarbamate-Functionalized Dendrimers as Ligands for Metal Complexes

Quentin J. McCubbin; Fiona J. Stoddart; Thomas Welton; Andrew J P White; David J. Williams

doi:10.1021/ic980067b

Dithiocarbamate-Functionalized Dendrimers as Ligands for Metal Complexes

Quentin J. McCubbin, Fiona J. Stoddart, Thomas Welton^*, Andrew J P White, David J. Williams

^*Corresponding author for this work

Chemistry

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32 Scopus citations

Abstract

Zeroth- and first-generation poly(amido)amine dendrimers have been functionalized with dithiocarbamate end groups and reacted with ruthenium complexes, to form metallodendrimers. Monomeric ruthenium dithiocarbamate complexes were also prepared as model compounds and their spectroscopic data compared with those of the metallodendrimers. The novel compounds were characterized using NMR spectroscopy (¹H and ¹³C) and mass spectrometry. The compound [Ru(S₂CNMe₂)(PPh₃)(η⁵-C ₅H₅)] has also been characterized crystallographically.

Original language	English (US)
Pages (from-to)	3753-3758
Number of pages	6
Journal	Inorganic chemistry
Volume	37
Issue number	15
DOIs	https://doi.org/10.1021/ic980067b
State	Published - Jul 27 1998

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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title = "Dithiocarbamate-Functionalized Dendrimers as Ligands for Metal Complexes",

abstract = "Zeroth- and first-generation poly(amido)amine dendrimers have been functionalized with dithiocarbamate end groups and reacted with ruthenium complexes, to form metallodendrimers. Monomeric ruthenium dithiocarbamate complexes were also prepared as model compounds and their spectroscopic data compared with those of the metallodendrimers. The novel compounds were characterized using NMR spectroscopy (1H and 13C) and mass spectrometry. The compound [Ru(S2CNMe2)(PPh3)(η5-C 5H5)] has also been characterized crystallographically.",

author = "McCubbin, {Quentin J.} and Stoddart, {Fiona J.} and Thomas Welton and White, {Andrew J P} and Williams, {David J.}",

year = "1998",

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T1 - Dithiocarbamate-Functionalized Dendrimers as Ligands for Metal Complexes

AU - McCubbin, Quentin J.

AU - Stoddart, Fiona J.

AU - Welton, Thomas

AU - White, Andrew J P

AU - Williams, David J.

PY - 1998/7/27

Y1 - 1998/7/27

N2 - Zeroth- and first-generation poly(amido)amine dendrimers have been functionalized with dithiocarbamate end groups and reacted with ruthenium complexes, to form metallodendrimers. Monomeric ruthenium dithiocarbamate complexes were also prepared as model compounds and their spectroscopic data compared with those of the metallodendrimers. The novel compounds were characterized using NMR spectroscopy (1H and 13C) and mass spectrometry. The compound [Ru(S2CNMe2)(PPh3)(η5-C 5H5)] has also been characterized crystallographically.

AB - Zeroth- and first-generation poly(amido)amine dendrimers have been functionalized with dithiocarbamate end groups and reacted with ruthenium complexes, to form metallodendrimers. Monomeric ruthenium dithiocarbamate complexes were also prepared as model compounds and their spectroscopic data compared with those of the metallodendrimers. The novel compounds were characterized using NMR spectroscopy (1H and 13C) and mass spectrometry. The compound [Ru(S2CNMe2)(PPh3)(η5-C 5H5)] has also been characterized crystallographically.

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JF - Inorganic Chemistry

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ER -

Dithiocarbamate-Functionalized Dendrimers as Ligands for Metal Complexes

Abstract

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