Does Marcus-Hush theory really work? Optical studies of intervalence transfer in acetylene-bridged biferrocene monocation at infinite dilution and at finite ionic strengths

Keyphrases

• Ionic Strength 100%
• Acetylene 100%
• Optical Studies 100%
• Monocation 100%
• Intervalence 100%
• Infinite Dilution 100%
• Marcus-Hush Theory 100%
• Biferrocene 100%
• Ion Pairs 66%
• Intervalence Charge Transfer 66%
• Methylene Chloride 66%
• Dielectric Saturation 66%
• Chromophore 33%
• High-order 33%
• Electrolyte 33%
• Electrolyte Concentration 33%
• Pressure-induced 33%
• Polar Solvents 33%
• Solvent Dependence 33%
• Optical Dielectric Constant 33%
• Saturation Effect 33%
• Dielectric Strength 33%
• Absorption Maxima 33%
• Solvent Behavior 33%
• Charge-transfer Energies 33%
• Ionic Association 33%
• Static Dielectric Constant 33%
• Small Variation 33%
• Ion-pairing Effect 33%
• Liquid Solvents 33%
• Chromophore Concentration 33%
• Dielectric Parameters 33%
• Marcus-Hush 33%
• Freezing Effect 33%

Chemistry

• Ionic Strength 100%
• Dilution 100%
• Dielectric Saturation 66%
• Dichloromethane 66%
• Chromophore 66%
• Energy Transfer 33%
• Dielectric Material 33%
• Polar Solvent 33%
• Dielectric Constant 33%
• Dielectric Strength 33%
• Absorption Maxima 33%
• Static Dielectric Constant 33%
• Permittivity 33%

Material Science

• Dilution 100%
• Dielectric Material 100%
• Permittivity 50%