Double-Walled Zn36@Zn104Multicomponent Senary Metal-Organic Polyhedral Framework and Its Isoreticular Evolution

Zhiyong Lu; Liting Du; Ruyong Guo; Guangbao Zhang; Jingui Duan; Jianfeng Zhang; Lin Han; Junfeng Bai; Joseph T. Hupp

doi:10.1021/jacs.1c08286

Double-Walled Zn₃₆@Zn₁₀₄Multicomponent Senary Metal-Organic Polyhedral Framework and Its Isoreticular Evolution

Zhiyong Lu^*, Liting Du, Ruyong Guo, Guangbao Zhang, Jingui Duan^*, Jianfeng Zhang, Lin Han, Junfeng Bai^*, Joseph T. Hupp

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Metal-organic polyhedral frameworks are attractive in gas storage and separation due to large voids with windows that can serve as traps for guest molecules. Introducing multivariant/multicomponent functionalities in them are ways of improving performances for certain targets. The high compatibility of organic linkers can generate multivariant MOFs, but by far, the diversity of secondary building units (SBUs) in a single metal-organic framework is still limited (no more than two in most cases). Here we report a new double-walled Zn36@Zn104 metal-organic polyhedral framework (HHU-8) with five types of topologically distinct SBUs and its isoreticular evolution to the Zn36@Zn136 counterpart (HHU-8s). Both MOFs are the first to be constructed with such high numbers of topologically distinct SBUs as well as topologically distinct nodes, and their formation and evolution provide new insight into SBU's controllability.

Original language	English (US)
Pages (from-to)	17942-17946
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	143
Issue number	43
DOIs	https://doi.org/10.1021/jacs.1c08286
State	Published - Nov 3 2021

Funding

This work was supported by the National Natural Science Foundation of China (Grants 21601047, 21501094, and 22171135), the Natural Science Fund of Jiangsu Province (Grant BK20150798), the Fundamental Research Funds for the Central Universities (Grant 2018B17614), and the China Scholarship Council (CSC) (Grant 201806715039). J.T.H. acknowledges support from The U.S. Department of Energy, Office of Science, Office of Basic Energy Science through Grant DE-FG02-08ER15967.

ASJC Scopus subject areas

General Chemistry
Biochemistry
Catalysis
Colloid and Surface Chemistry

Access to Document

10.1021/jacs.1c08286

Cite this

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title = "Double-Walled Zn36@Zn104Multicomponent Senary Metal-Organic Polyhedral Framework and Its Isoreticular Evolution",

abstract = "Metal-organic polyhedral frameworks are attractive in gas storage and separation due to large voids with windows that can serve as traps for guest molecules. Introducing multivariant/multicomponent functionalities in them are ways of improving performances for certain targets. The high compatibility of organic linkers can generate multivariant MOFs, but by far, the diversity of secondary building units (SBUs) in a single metal-organic framework is still limited (no more than two in most cases). Here we report a new double-walled Zn36@Zn104 metal-organic polyhedral framework (HHU-8) with five types of topologically distinct SBUs and its isoreticular evolution to the Zn36@Zn136 counterpart (HHU-8s). Both MOFs are the first to be constructed with such high numbers of topologically distinct SBUs as well as topologically distinct nodes, and their formation and evolution provide new insight into SBU's controllability.",

author = "Zhiyong Lu and Liting Du and Ruyong Guo and Guangbao Zhang and Jingui Duan and Jianfeng Zhang and Lin Han and Junfeng Bai and Hupp, {Joseph T.}",

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AU - Duan, Jingui

AU - Zhang, Jianfeng

AU - Han, Lin

AU - Bai, Junfeng

AU - Hupp, Joseph T.

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PY - 2021/11/3

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N2 - Metal-organic polyhedral frameworks are attractive in gas storage and separation due to large voids with windows that can serve as traps for guest molecules. Introducing multivariant/multicomponent functionalities in them are ways of improving performances for certain targets. The high compatibility of organic linkers can generate multivariant MOFs, but by far, the diversity of secondary building units (SBUs) in a single metal-organic framework is still limited (no more than two in most cases). Here we report a new double-walled Zn36@Zn104 metal-organic polyhedral framework (HHU-8) with five types of topologically distinct SBUs and its isoreticular evolution to the Zn36@Zn136 counterpart (HHU-8s). Both MOFs are the first to be constructed with such high numbers of topologically distinct SBUs as well as topologically distinct nodes, and their formation and evolution provide new insight into SBU's controllability.

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Double-Walled Zn₃₆@Zn₁₀₄Multicomponent Senary Metal-Organic Polyhedral Framework and Its Isoreticular Evolution

Abstract

Funding

ASJC Scopus subject areas

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CCDC 2088199: Experimental Crystal Structure Determination

CCDC 2088198: Experimental Crystal Structure Determination

CCDC 2113956: Experimental Crystal Structure Determination

Cite this

Double-Walled Zn36@Zn104Multicomponent Senary Metal-Organic Polyhedral Framework and Its Isoreticular Evolution

Abstract

Funding

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 2088199: Experimental Crystal Structure Determination

CCDC 2088198: Experimental Crystal Structure Determination

CCDC 2113956: Experimental Crystal Structure Determination

Cite this

Double-Walled Zn₃₆@Zn₁₀₄Multicomponent Senary Metal-Organic Polyhedral Framework and Its Isoreticular Evolution