Doubly Encircled and Double‐Stranded Pseudorotaxanes

Peter R. Ashton, Peter T. Glink, Cesare Schiavo, J. Fraser Stoddart*, Ewan J.T. Chrystal, Stephen Menzer, David J. Williams, Peter A. Tasker

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

92 Scopus citations

Abstract

Novel supramolecular architectures formed by self‐assembly of three or four charged and neutral species have been prepared and characterized. In both the solution and solid states the two dibenzylammonium ions in the dicationic 1:2 complex 1 are threaded simultaneously through bis‐para‐phenylene[34]crown‐10. This macrocyclic polyether forms a 2:2 complex with α,α′‐bis(benzylammonium)‐para‐xylylene bis(hexafluorophosphate) in the solid state. (Figure Presented.)

Original languageEnglish (US)
Pages (from-to)1869-1871
Number of pages3
JournalAngewandte Chemie International Edition in English
Volume34
Issue number17
DOIs
StatePublished - Sep 15 1995

Keywords

  • crown ethers
  • molecular recognition
  • rotaxanes
  • self‐assembly

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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