This paper describes a new class of homochiral salen-based infinite coordination polymers (ICPs) and the discovery of a novel and pseudo-reversible solvent-induced crystallization process. The solvent, methanol in this case, induces such a transformation through a change in the coordination environment around the metal bridging the metallo-salen portion of the complex. This transformation has allowed us to use X-ray methods to structurally characterize the crystalline product and through spectroscopic comparisons better understand the connectivity and structure of the amorphous ICP particles from which it is derived.
ASJC Scopus subject areas
- Colloid and Surface Chemistry