Dynamics of NCS Formation from Photolysis of RNCS

Fredrick J Northrup; T J Sears

Dynamics of NCS Formation from Photolysis of RNCS

Chemistry

Research output: Contribution to conference › Abstract › peer-review

Abstract

Laser induced fluorescence (LIF) was used to probe the internal energy modes of NCS resulting from the 248 nm photolysis of compounds RNCS (R=Me, Et). Accurate spectroscopic constants were determined for the excited vibrational levels for the first time. The NCS fragment was found to be highly excited in all three vibrational modes. Rotational motion was not as highly excited. The dissociation was found preferentially populate the upper spin-orbit component of the ground 2 state.

Original language	English
State	Published - Oct 20 1988
Event	Advances in Laser Science-IV,Proceedings of the Fourth International Laser Science Conference - Atlanta, GA Duration: Oct 20 1988 → …

Conference

Conference	Advances in Laser Science-IV,Proceedings of the Fourth International Laser Science Conference
Period	10/20/88 → …

Cite this

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title = "Dynamics of NCS Formation from Photolysis of RNCS",

abstract = "Laser induced fluorescence (LIF) was used to probe the internal energy modes of NCS resulting from the 248 nm photolysis of compounds RNCS (R=Me, Et). Accurate spectroscopic constants were determined for the excited vibrational levels for the first time. The NCS fragment was found to be highly excited in all three vibrational modes. Rotational motion was not as highly excited. The dissociation was found preferentially populate the upper spin-orbit component of the ground 2 state.",

author = "Northrup, {Fredrick J} and Sears, {T J}",

year = "1988",

month = oct,

day = "20",

language = "English",

note = "Advances in Laser Science-IV,Proceedings of the Fourth International Laser Science Conference ; Conference date: 20-10-1988",

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TY - CONF

T1 - Dynamics of NCS Formation from Photolysis of RNCS

AU - Northrup, Fredrick J

AU - Sears, T J

PY - 1988/10/20

Y1 - 1988/10/20

N2 - Laser induced fluorescence (LIF) was used to probe the internal energy modes of NCS resulting from the 248 nm photolysis of compounds RNCS (R=Me, Et). Accurate spectroscopic constants were determined for the excited vibrational levels for the first time. The NCS fragment was found to be highly excited in all three vibrational modes. Rotational motion was not as highly excited. The dissociation was found preferentially populate the upper spin-orbit component of the ground 2 state.

AB - Laser induced fluorescence (LIF) was used to probe the internal energy modes of NCS resulting from the 248 nm photolysis of compounds RNCS (R=Me, Et). Accurate spectroscopic constants were determined for the excited vibrational levels for the first time. The NCS fragment was found to be highly excited in all three vibrational modes. Rotational motion was not as highly excited. The dissociation was found preferentially populate the upper spin-orbit component of the ground 2 state.

M3 - Abstract

T2 - Advances in Laser Science-IV,Proceedings of the Fourth International Laser Science Conference

Y2 - 20 October 1988

ER -

Dynamics of NCS Formation from Photolysis of RNCS

Abstract

Conference

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