Effect of high pressure on some electrophysical properties of polymers: Polyconjugated systems doped by iodine

V. A. Zhorin*, S. I. Beshenko, Yu A. Berlin, N. S. Enikolopian

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

The effect of pressure P up to 2.5 × 103 MPa on the dielectric constant ε and conductivity G of a number of conjugated polymers doped by iodine has been studied. Polyphenylacetylene prepared with FeAcAc, polyphenylacetylene obtained with Ziegler catalyst, anionic polydiphenylacetylene, and polydiphenylbutadiene were chosen for investigation. It has been found that after doping the values ε and G increase and strongly depend on P. The possible mechanism of this phenomenon has been discussed.

Original languageEnglish (US)
Pages (from-to)2467-2472
Number of pages6
JournalJournal of Applied Polymer Science
Volume28
Issue number8
DOIs
StatePublished - Aug 1983

ASJC Scopus subject areas

  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Polymers and Plastics
  • Materials Chemistry

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