Effect of high pressure on some electrophysical properties of polymers: Polyconjugated systems doped by iodine

V. A. Zhorin; S. I. Beshenko; Yu A. Berlin; N. S. Enikolopian

doi:10.1002/app.1983.070280801

Effect of high pressure on some electrophysical properties of polymers: Polyconjugated systems doped by iodine

V. A. Zhorin^*, S. I. Beshenko, Yu A. Berlin, N. S. Enikolopian

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The effect of pressure P up to 2.5 × 10³ MPa on the dielectric constant ε and conductivity G of a number of conjugated polymers doped by iodine has been studied. Polyphenylacetylene prepared with FeAcAc, polyphenylacetylene obtained with Ziegler catalyst, anionic polydiphenylacetylene, and polydiphenylbutadiene were chosen for investigation. It has been found that after doping the values ε and G increase and strongly depend on P. The possible mechanism of this phenomenon has been discussed.

Original language	English (US)
Pages (from-to)	2467-2472
Number of pages	6
Journal	Journal of Applied Polymer Science
Volume	28
Issue number	8
DOIs	https://doi.org/10.1002/app.1983.070280801
State	Published - Aug 1983

ASJC Scopus subject areas

Chemistry(all)
Surfaces, Coatings and Films
Polymers and Plastics
Materials Chemistry

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10.1002/app.1983.070280801

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abstract = "The effect of pressure P up to 2.5 × 103 MPa on the dielectric constant ε and conductivity G of a number of conjugated polymers doped by iodine has been studied. Polyphenylacetylene prepared with FeAcAc, polyphenylacetylene obtained with Ziegler catalyst, anionic polydiphenylacetylene, and polydiphenylbutadiene were chosen for investigation. It has been found that after doping the values ε and G increase and strongly depend on P. The possible mechanism of this phenomenon has been discussed.",

author = "Zhorin, {V. A.} and Beshenko, {S. I.} and Berlin, {Yu A.} and Enikolopian, {N. S.}",

year = "1983",

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T2 - Polyconjugated systems doped by iodine

AU - Zhorin, V. A.

AU - Beshenko, S. I.

AU - Berlin, Yu A.

AU - Enikolopian, N. S.

PY - 1983/8

Y1 - 1983/8

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AB - The effect of pressure P up to 2.5 × 103 MPa on the dielectric constant ε and conductivity G of a number of conjugated polymers doped by iodine has been studied. Polyphenylacetylene prepared with FeAcAc, polyphenylacetylene obtained with Ziegler catalyst, anionic polydiphenylacetylene, and polydiphenylbutadiene were chosen for investigation. It has been found that after doping the values ε and G increase and strongly depend on P. The possible mechanism of this phenomenon has been discussed.

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JO - Journal of Applied Polymer Science

JF - Journal of Applied Polymer Science

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ER -

Effect of high pressure on some electrophysical properties of polymers: Polyconjugated systems doped by iodine

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