Effects of strained bicyclic annelation on the benzene nucleus: The X-ray crystal structures of a triphenylene and two anthracene derivatives

Francesca Cardullo; Daniele Giuffrida; Franz H. Kohnke; Françisco M. Raymo; J. Fraser Stoddart; David J. Williams

doi:10.1002/anie.199603391

Effects of strained bicyclic annelation on the benzene nucleus: The X-ray crystal structures of a triphenylene and two anthracene derivatives

Francesca Cardullo, Daniele Giuffrida, Franz H. Kohnke, Françisco M. Raymo, J. Fraser Stoddart, David J. Williams

Chemistry

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Pronounced bond length alternation in the central aromatic ring is the eye-catching structural feature of triepoxytriphenylene 1. By contrast, no significant bond length alternation is observed in the linearly bisannelated compounds 2 and 3. The key difference is ascribed to the position of annelations with the bicyclic units (Image Presented).

Original language	English (US)
Pages (from-to)	339-341
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	35
Issue number	3
DOIs	https://doi.org/10.1002/anie.199603391
State	Published - Jan 1 1996

Keywords

Bond-length alternation
Mills-Nixon effect
Polycycles
Strained rings
Triepoxytriphenylenes

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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abstract = "Pronounced bond length alternation in the central aromatic ring is the eye-catching structural feature of triepoxytriphenylene 1. By contrast, no significant bond length alternation is observed in the linearly bisannelated compounds 2 and 3. The key difference is ascribed to the position of annelations with the bicyclic units (Image Presented).",

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Effects of strained bicyclic annelation on the benzene nucleus : The X-ray crystal structures of a triphenylene and two anthracene derivatives. / Cardullo, Francesca; Giuffrida, Daniele; Kohnke, Franz H.; Raymo, Françisco M.; Stoddart, J. Fraser; Williams, David J.

In: Angewandte Chemie - International Edition, Vol. 35, No. 3, 01.01.1996, p. 339-341.

Research output: Contribution to journal › Article › peer-review

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