Effects of vertical hydrodynamic mixing on photomineralization of dissolved organic carbon in arctic surface waters

Angang Li, Antoine F. Aubeneau*, Tyler King, Rose M. Cory, Bethany T. Neilson, Diogo Bolster, Aaron I. Packman

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

6 Scopus citations


Photomineralization, the transformation of dissolved organic carbon (DOC) to CO2 by sunlight, is an important source of CO2 in arctic surface waters. However, quantifying the role of photomineralization in inland waters is limited by the understanding of hydrologic controls on this process. To bridge this gap, this study evaluates mixing limitations, i.e., whether and by how much vertical mixing limits the depth-integrated photomineralization rate, in freshwater systems. We developed a conceptual model to qualitatively assess mixing limitations across the range of light attenuation and hydrologic conditions observed in freshwaters. For the common case of exponential light attenuation over depth, we developed a mathematical model to quantify mixing limitation, and used this model to assess a range of arctic freshwater systems. The results demonstrate that mixing limitations are important when there is significant light attenuation by suspended sediment (SS), which is the case in some arctic, boreal and temperate waters. Mixing limitation is pronounced when light attenuation over depth is strong and when the photomineralization rate at the water surface exceeds the vertical mixing rate. Arctic streams and rivers have strong vertical mixing relative to surface photomineralization, such that model results demonstrate no mixing limitation regardless of how much SS is present. Our analysis indicates that well-mixed assumptions used in prior work are valid in many, but not all, arctic surface waters. The effects of mixing limitations in reducing the photomineralization rate must be considered in arctic lakes with high SS concentrations.

Original languageEnglish (US)
Pages (from-to)748-760
Number of pages13
JournalEnvironmental Science: Processes and Impacts
Issue number4
StatePublished - Apr 2019

ASJC Scopus subject areas

  • Environmental Chemistry
  • Public Health, Environmental and Occupational Health
  • Management, Monitoring, Policy and Law

Fingerprint Dive into the research topics of 'Effects of vertical hydrodynamic mixing on photomineralization of dissolved organic carbon in arctic surface waters'. Together they form a unique fingerprint.

Cite this