Efficient carbene and carbyne formation in molybdenum(0) and tungsten(0) dinitrogen complexes

Yalan Ning; Robert D.J. Froese; Peter Margl; Edward L. Lee; Sonbinh T. Nguyen; Thomas H. Peterson; Nicole Wagner; Charlotte L. Stern; Amy A. Sarjeant

doi:10.1021/om4006214

Efficient carbene and carbyne formation in molybdenum(0) and tungsten(0) dinitrogen complexes

Yalan Ning, Robert D.J. Froese, Peter Margl, Edward L. Lee, Sonbinh T. Nguyen^*, Thomas H. Peterson, Nicole Wagner, Charlotte L. Stern, Amy A. Sarjeant

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Zerovalent group 6 dinitrogen phosphine complexes react with 3,3-diphenylcyclopropene to give vinylcarbyne hydride complexes that have been characterized crystallographically. Computational studies indicate that the observed products resulted from the α-migration and rearrangement of an initially formed vinylcarbene.

Original language	English (US)
Pages (from-to)	1120-1125
Number of pages	6
Journal	Organometallics
Volume	33
Issue number	5
DOIs	https://doi.org/10.1021/om4006214
State	Published - Mar 10 2014

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om4006214

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title = "Efficient carbene and carbyne formation in molybdenum(0) and tungsten(0) dinitrogen complexes",

abstract = "Zerovalent group 6 dinitrogen phosphine complexes react with 3,3-diphenylcyclopropene to give vinylcarbyne hydride complexes that have been characterized crystallographically. Computational studies indicate that the observed products resulted from the α-migration and rearrangement of an initially formed vinylcarbene.",

author = "Yalan Ning and Froese, {Robert D.J.} and Peter Margl and Lee, {Edward L.} and Nguyen, {Sonbinh T.} and Peterson, {Thomas H.} and Nicole Wagner and Stern, {Charlotte L.} and Sarjeant, {Amy A.}",

year = "2014",

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doi = "10.1021/om4006214",

language = "English (US)",

volume = "33",

pages = "1120--1125",

journal = "Organometallics",

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T1 - Efficient carbene and carbyne formation in molybdenum(0) and tungsten(0) dinitrogen complexes

AU - Ning, Yalan

AU - Froese, Robert D.J.

AU - Margl, Peter

AU - Lee, Edward L.

AU - Nguyen, Sonbinh T.

AU - Peterson, Thomas H.

AU - Wagner, Nicole

AU - Stern, Charlotte L.

AU - Sarjeant, Amy A.

PY - 2014/3/10

Y1 - 2014/3/10

N2 - Zerovalent group 6 dinitrogen phosphine complexes react with 3,3-diphenylcyclopropene to give vinylcarbyne hydride complexes that have been characterized crystallographically. Computational studies indicate that the observed products resulted from the α-migration and rearrangement of an initially formed vinylcarbene.

AB - Zerovalent group 6 dinitrogen phosphine complexes react with 3,3-diphenylcyclopropene to give vinylcarbyne hydride complexes that have been characterized crystallographically. Computational studies indicate that the observed products resulted from the α-migration and rearrangement of an initially formed vinylcarbene.

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U2 - 10.1021/om4006214

DO - 10.1021/om4006214

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JF - Organometallics

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ER -

Efficient carbene and carbyne formation in molybdenum(0) and tungsten(0) dinitrogen complexes

Abstract

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CCDC 832214: Experimental Crystal Structure Determination

CCDC 832213: Experimental Crystal Structure Determination

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Efficient carbene and carbyne formation in molybdenum(0) and tungsten(0) dinitrogen complexes

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 832214: Experimental Crystal Structure Determination

CCDC 832213: Experimental Crystal Structure Determination

Cite this