@article{e9e93045c212483cbba39ba44ba4eaf3,
title = "Efficient catalytic greenhouse gas-free hydrogen and aldehyde formation from aqueous alcohol solutions",
abstract = "Hydrogen is an ideal fuel candidate due to its clean combustion characteristics. Here we report an inexpensive and sustainable Mo-based, carbon-supported catalyst that generates H2 and the corresponding aldehyde from aqueous methanol or ethanol at high rates with negligible greenhouse gas co-production. The aldehyde coproducts lend value to this process without producing CO2.",
author = "Lohr, {Tracy L.} and Mouat, {Aidan R.} and Schweitzer, {Neil M.} and Stair, {Peter C.} and Massimiliano Delferro and Marks, {Tobin J.}",
note = "Funding Information: Financial support by the Chemical Sciences, Geosciences, and Biosciences Division, U.S. Department of Energy through grant DE FG02-03ER15457 to the Institute for Catalysis in Energy Processes (ICEP) at Northwestern University. NSF grant CHE-1213235 supported T. L. L. and provided some reactor equipment. The authors also acknowledge the Integrated Molecular Structure Education and Research Center (IMSERC), Department of Chemistry, Northwestern University, for access to MS and NMR instrumentation - specifically for access to Agilent 6210A LC-ToF, and Bruker Autoflex III MALDI-ToF mass spectrometers, Agilent MR400 DD2, and an INOVA 500 MHz NMR spectrometers previously purchased with funds (either partially or entirely) from the State of Illinois, Northwestern U., the Northwestern International Institute of Nanotechnology, and NSF (grant no. CHE-9871268, 1998), respectively. The CleanCat Core facility acknowledges funding from the DOE (grant no. DE-FG02-03ER15457 and DE-AC02-06CH11357). We thank Dr S. H. Goudarzi (IMSERC-NU) for the support on ESI-MS measurements. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2017.",
year = "2017",
month = jul,
doi = "10.1039/c6ee03739a",
language = "English (US)",
volume = "10",
pages = "1558--1562",
journal = "Energy and Environmental Science",
issn = "1754-5692",
publisher = "Royal Society of Chemistry",
number = "7",
}
