Abstract
(Chemical Equation Presented) A series of unconventional twisted π-electron system molecules has been synthesized via Suzuki cross-coupling of two sterically hindered arenes. Crystallographic analysis of these molecules reveals a large ring-ring dihedral twist angle (87°) and a highly charge-separated zwitterionic ground state. An efficient conversion of phenols into aryl halides is also reported.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 3721-3724 |
| Number of pages | 4 |
| Journal | Organic Letters |
| Volume | 7 |
| Issue number | 17 |
| DOIs | |
| State | Published - Aug 18 2005 |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
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CCDC 274102: Experimental Crystal Structure Determination
Kang, H. (Creator), Facchetti, A. (Creator), Stern, C. L. (Creator), Marks, T. J. (Creator), Rheingold, A. L. (Creator) & Kassel, W. S. (Creator), Cambridge Crystallographic Data Centre, 2006
DOI: 10.5517/cc9670q, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc9670q&sid=DataCite
Dataset
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CCDC 274104: Experimental Crystal Structure Determination
Kang, H. (Creator), Facchetti, A. (Creator), Stern, C. L. (Creator), Rheingold, A. L. (Creator), Kassel, W. S. (Creator) & Marks, T. J. (Creator), Cambridge Crystallographic Data Centre, 2006
DOI: 10.5517/cc9672s, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc9672s&sid=DataCite
Dataset