Elasticity, fracture and thermoreversible gelation of highly filled physical gels

P. L. Drzal*, K. R. Shull

*Corresponding author for this work

Research output: Contribution to journalArticle

8 Scopus citations

Abstract

We describe a physically associating triblock copolymer-based gel that exhibits a reversible transition between solid and liquid states at a temperature of approximately 55° C. The thermal transition of the gel enables us to compare the properties of liquid suspensions and elastic composites with identical particle loadings, with particle volume fractions as large as 0.55. The suspension viscosity and the composite elasticity scale in a similar manner with the overall particle volume fraction, a result that is rationalized in terms of an effective strain amplification factor that depends only on the particle loading. Measured values of the strain amplification factor are in good agreement with the expected form for well-dispersed spheres. We also find that the elastic composites are exceptionally strong, with fracture strengths that exceed the modulus of the base gel by a factor of 100 or more. Deviations from purely elastic behavior became important for high particle volume fractions, and were probed by stress relaxation experiments.

Original languageEnglish (US)
Pages (from-to)477-483
Number of pages7
JournalEuropean Physical Journal E
Volume17
Issue number4
DOIs
StatePublished - Aug 1 2005

ASJC Scopus subject areas

  • Biotechnology
  • Biophysics
  • Chemistry(all)
  • Materials Science(all)
  • Surfaces and Interfaces

Fingerprint Dive into the research topics of 'Elasticity, fracture and thermoreversible gelation of highly filled physical gels'. Together they form a unique fingerprint.

  • Cite this