@article{a10fb059dbe84b95944578a22ac553d3,
title = "Electrocatalytic Rate Alignment Enhances Syngas Generation",
abstract = " A rate-aligned electrocatalyst is reported that provides tunable access to a range of synthesis gas compositions as a function of potential. These electrocatalysts comprise a Au CO-generating component and a Co, Fe, or Ni H 2 -generating component. The orthogonal integration of these two materials enhances the ability to tune syngas ratio, such that a wide range of desirable syngas compositions are accessed over a narrow potential range, all at high geometric current densities.",
keywords = "carbon dioxide, CO reduction, electrocatalysis, H evolution, heterogeneous catalysis, synthesis gas",
author = "Ross, {Michael B.} and Yifan Li and {De Luna}, Phil and Dohyung Kim and Sargent, {Edward H.} and Peidong Yang",
note = "Funding Information: This work was supported by the CIFAR Bio-Inspired Solar Energy Program and by the Director, Office of Science , Office of Basic Energy Sciences , Chemical Sciences, Geosciences, and Biosciences Division , of the U.S. Department of Energy under contract no. DE-AC02-05CH11231 within the Catalysis Research Program (FWP no. CH030201). XAS data were collected at the Soft X-ray Microcharacterization Beamline (SXRMB) at the Canadian Light Source with the assistance of Dr. Yongfeng Hu. Work at the Molecular Foundry was supported by the Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy under contract no. DE-AC02-05CH11231 . Calculations were performed on the SOSCIP Consortium's Blue Gene/Q computing platform. SOSCIP is funded by the Federal Economic Development Agency of Southern Ontario , the Province of Ontario, IBM Canada Ltd ., Ontario Centres of Excellence , Mitacs, and 15 Ontario academic member institutions. M.B.R. gratefully acknowledges support from the CIFAR Bio-Inspired Solar Energy Program (Postdoctoral Fellowship). P.D.L. wishes to thank the Natural Sciences and Engineering Research Council (NSERC) of Canada for support in the form of the Canadian Graduate Scholarship – Doctoral award. D.K. acknowledges support from Samsung Scholarship. Funding Information: This work was supported by the CIFAR Bio-Inspired Solar Energy Program and by the Director, Office of Science, Office of Basic Energy Sciences, Chemical Sciences, Geosciences, and Biosciences Division, of the U.S. Department of Energy under contract no. DE-AC02-05CH11231 within the Catalysis Research Program (FWP no. CH030201). XAS data were collected at the Soft X-ray Microcharacterization Beamline (SXRMB) at the Canadian Light Source with the assistance of Dr. Yongfeng Hu. Work at the Molecular Foundry was supported by the Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy under contract no. DE-AC02-05CH11231. Calculations were performed on the SOSCIP Consortium's Blue Gene/Q computing platform. SOSCIP is funded by the Federal Economic Development Agency of Southern Ontario, the Province of Ontario, IBM Canada Ltd., Ontario Centres of Excellence, Mitacs, and 15 Ontario academic member institutions. M.B.R. gratefully acknowledges support from the CIFAR Bio-Inspired Solar Energy Program (Postdoctoral Fellowship). P.D.L. wishes to thank the Natural Sciences and Engineering Research Council (NSERC) of Canada for support in the form of the Canadian Graduate Scholarship – Doctoral award. D.K. acknowledges support from Samsung Scholarship. Publisher Copyright: {\textcopyright} 2018 Elsevier Inc.",
year = "2019",
month = jan,
day = "16",
doi = "10.1016/j.joule.2018.09.013",
language = "English (US)",
volume = "3",
pages = "257--264",
journal = "Joule",
issn = "2542-4351",
publisher = "Cell Press",
number = "1",
}