A rare three-dimensional catecholate-based Ce(iii) metal-organic framework (MOF), denoted as NU-1701, has been synthesized and crystallographically characterized. Density functional theory calculations highlight various possible electronic transitions that may present in NU-1701. These transitions are competitive and indicate increased lanthanide character of Ce(iii).
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
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Knapp, J. G. (Contributor), Ray, D. (Contributor), Calio, P. B. (Contributor), Wasson, M. C. (Contributor), Scott, T. R. (Contributor), Gagliardi, L. (Contributor), Farha, O. K. (Contributor) & Farha, O. K. (Contributor), Cambridge Crystallographic Data Centre, 2021