The electronic structure of the oxyfluorides YOF, LaOF, and EuOF has been studied by photoelectron and X-ray emission spectroscopy. A satisfactory interpretation of the spectra is obtained by self-consistent one-electron molecular orbital models for (RO//4F//4)**9** minus clusters. Calculations were made using the local density formalism, as implemented in the discrete variational DV-X delta scheme. Qualitative interpretations of luminescence properties of these materials are obtained from the MO model.
|Original language||English (US)|
|Number of pages||12|
|Journal||Physica B: Physics of Condensed Matter & C: Atomic, Molecular and Plasma Physics, Optics|
|State||Published - 1980|
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