Abstract
Redox "B" ess: Rational design of a new series of boron-functionalized NiIII/NiIV-bis (dicarbollide) clusters results in a family of robust and tunable redox shuttles (see diagram; EDG and EWG denote electron-donating and -withdrawing groups, respectively). This offers a means to rationally control the redox properties in dye-sensitized solar cells (DSCs), leading to exceptionally high open-circuit voltages.
Original language | English (US) |
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Pages (from-to) | 5339-5343 |
Number of pages | 5 |
Journal | Angewandte Chemie - International Edition |
Volume | 49 |
Issue number | 31 |
DOIs | |
State | Published - Jul 19 2010 |
Keywords
- Bis (dicarbollide)s
- Carboranes
- Dye-sensitized solar cells
- Redox shuttles
- Solar cells
ASJC Scopus subject areas
- Catalysis
- General Chemistry
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CCDC 769147: Experimental Crystal Structure Determination
Spokoyny, A. M. (Creator), Li, T. C. (Creator), Farha, O. K. (Creator), Machan, C. W. (Creator), She, C. (Creator), Stern, C. L. (Creator), Marks, T. J. (Creator), Hupp, J. T. (Creator) & Mirkin, C. A. (Creator), Cambridge Crystallographic Data Centre, 2010
DOI: 10.5517/ccttc65, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccttc65&sid=DataCite
Dataset
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CCDC 769145: Experimental Crystal Structure Determination
Spokoyny, A. M. (Creator), Li, T. C. (Creator), Farha, O. K. (Creator), Machan, C. W. (Creator), She, C. (Creator), Stern, C. L. (Creator), Marks, T. J. (Creator), Hupp, J. T. (Creator) & Mirkin, C. A. (Creator), Cambridge Crystallographic Data Centre, 2010
DOI: 10.5517/ccttc43, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccttc43&sid=DataCite
Dataset
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CCDC 769148: Experimental Crystal Structure Determination
Spokoyny, A. M. (Creator), Li, T. C. (Creator), Farha, O. K. (Creator), Machan, C. W. (Creator), She, C. (Creator), Stern, C. L. (Creator), Marks, T. J. (Creator), Hupp, J. T. (Creator) & Mirkin, C. A. (Creator), Cambridge Crystallographic Data Centre, 2010
DOI: 10.5517/ccttc76, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccttc76&sid=DataCite
Dataset