Electronic tuning of nickel-based bis(dicarbollide) redox shuttles in dye-sensitized solar cells

Alexander M. Spokoyny; Tina C. Li; Omar K. Farha; Charles W. Machan; Chunxing She; Charlotte L. Stern; Tobin J. Marks; Joseph T. Hupp; Chad A. Mirkin

doi:10.1002/anie.201002181

Electronic tuning of nickel-based bis(dicarbollide) redox shuttles in dye-sensitized solar cells

Alexander M. Spokoyny, Tina C. Li, Omar K. Farha, Charles W. Machan, Chunxing She, Charlotte L. Stern, Tobin J. Marks, Joseph T. Hupp, Chad A. Mirkin

Chemistry

Research output: Contribution to journal › Article › peer-review

120 Scopus citations

Abstract

Redox "B" ess: Rational design of a new series of boron-functionalized Ni^III/Ni^IV-bis (dicarbollide) clusters results in a family of robust and tunable redox shuttles (see diagram; EDG and EWG denote electron-donating and -withdrawing groups, respectively). This offers a means to rationally control the redox properties in dye-sensitized solar cells (DSCs), leading to exceptionally high open-circuit voltages.

Original language	English (US)
Pages (from-to)	5339-5343
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	31
DOIs	https://doi.org/10.1002/anie.201002181
State	Published - Jul 19 2010

Keywords

Bis (dicarbollide)s
Carboranes
Dye-sensitized solar cells
Redox shuttles
Solar cells

ASJC Scopus subject areas

Catalysis
General Chemistry

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1002/anie.201002181

Cite this

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title = "Electronic tuning of nickel-based bis(dicarbollide) redox shuttles in dye-sensitized solar cells",

abstract = "Redox {"}B{"} ess: Rational design of a new series of boron-functionalized NiIII/NiIV-bis (dicarbollide) clusters results in a family of robust and tunable redox shuttles (see diagram; EDG and EWG denote electron-donating and -withdrawing groups, respectively). This offers a means to rationally control the redox properties in dye-sensitized solar cells (DSCs), leading to exceptionally high open-circuit voltages.",

keywords = "Bis (dicarbollide)s, Carboranes, Dye-sensitized solar cells, Redox shuttles, Solar cells",

author = "Spokoyny, \{Alexander M.\} and Li, \{Tina C.\} and Farha, \{Omar K.\} and Machan, \{Charles W.\} and Chunxing She and Stern, \{Charlotte L.\} and Marks, \{Tobin J.\} and Hupp, \{Joseph T.\} and Mirkin, \{Chad A.\}",

year = "2010",

month = jul,

day = "19",

doi = "10.1002/anie.201002181",

language = "English (US)",

volume = "49",

pages = "5339--5343",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "31",

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TY - JOUR

T1 - Electronic tuning of nickel-based bis(dicarbollide) redox shuttles in dye-sensitized solar cells

AU - Spokoyny, Alexander M.

AU - Li, Tina C.

AU - Farha, Omar K.

AU - Machan, Charles W.

AU - She, Chunxing

AU - Stern, Charlotte L.

AU - Marks, Tobin J.

AU - Hupp, Joseph T.

AU - Mirkin, Chad A.

PY - 2010/7/19

Y1 - 2010/7/19

N2 - Redox "B" ess: Rational design of a new series of boron-functionalized NiIII/NiIV-bis (dicarbollide) clusters results in a family of robust and tunable redox shuttles (see diagram; EDG and EWG denote electron-donating and -withdrawing groups, respectively). This offers a means to rationally control the redox properties in dye-sensitized solar cells (DSCs), leading to exceptionally high open-circuit voltages.

AB - Redox "B" ess: Rational design of a new series of boron-functionalized NiIII/NiIV-bis (dicarbollide) clusters results in a family of robust and tunable redox shuttles (see diagram; EDG and EWG denote electron-donating and -withdrawing groups, respectively). This offers a means to rationally control the redox properties in dye-sensitized solar cells (DSCs), leading to exceptionally high open-circuit voltages.

KW - Bis (dicarbollide)s

KW - Carboranes

KW - Dye-sensitized solar cells

KW - Redox shuttles

KW - Solar cells

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U2 - 10.1002/anie.201002181

DO - 10.1002/anie.201002181

M3 - Article

C2 - 20586090

AN - SCOPUS:77954858011

SN - 1433-7851

VL - 49

SP - 5339

EP - 5343

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 31

ER -

Electronic tuning of nickel-based bis(dicarbollide) redox shuttles in dye-sensitized solar cells

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

Access to Document

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CCDC 769147: Experimental Crystal Structure Determination

CCDC 769145: Experimental Crystal Structure Determination

CCDC 769148: Experimental Crystal Structure Determination

Cite this

Electronic tuning of nickel-based bis(dicarbollide) redox shuttles in dye-sensitized solar cells

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 769147: Experimental Crystal Structure Determination

CCDC 769145: Experimental Crystal Structure Determination

CCDC 769148: Experimental Crystal Structure Determination

Cite this