Abstract
Redox "B" ess: Rational design of a new series of boron-functionalized NiIII/NiIV-bis (dicarbollide) clusters results in a family of robust and tunable redox shuttles (see diagram; EDG and EWG denote electron-donating and -withdrawing groups, respectively). This offers a means to rationally control the redox properties in dye-sensitized solar cells (DSCs), leading to exceptionally high open-circuit voltages.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 5339-5343 |
| Number of pages | 5 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 49 |
| Issue number | 31 |
| DOIs | |
| State | Published - Jul 19 2010 |
Keywords
- Bis (dicarbollide)s
- Carboranes
- Dye-sensitized solar cells
- Redox shuttles
- Solar cells
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
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Cite this
Spokoyny, A. M., Li, T. C., Farha, O. K., Machan, C. W., She, C., Stern, C. L., Marks, T. J., Hupp, J. T., & Mirkin, C. A. (2010). Electronic tuning of nickel-based bis(dicarbollide) redox shuttles in dye-sensitized solar cells. Angewandte Chemie - International Edition, 49(31), 5339-5343. https://doi.org/10.1002/anie.201002181