Electrophilic Addition of a Proton to 1, 2-Bis(Carbomethoxy)Acetylene Inserted into the Iron-Iron Bond of [(μ-SCH3)Fe(CO)(P(CH3)3)2]2. X-Ray Structure at -162°C of the Reaction Product, a Chelated 1, 2-Bis(Carbomethoxy)Ethylene Complex, [((μ-SCH3)Fe(CO)(P(CH3)3)2)2(CH3COOCCHCOOCH3)][B(C6H5)4]

J. J. Bonnet, R. Mathieu, James A Ibers

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Dive into the research topics of 'Electrophilic Addition of a Proton to 1, 2-Bis(Carbomethoxy)Acetylene Inserted into the Iron-Iron Bond of [(μ-SCH<sub>3</sub>)Fe(CO)(P(CH<sub>3</sub>)<sub>3</sub>)<sub>2</sub>]<sub>2</sub>. X-Ray Structure at -162°C of the Reaction Product, a Chelated 1, 2-Bis(Carbomethoxy)Ethylene Complex, [((μ-SCH<sub>3</sub>)Fe(CO)(P(CH<sub>3</sub>)<sub>3</sub>)<sub>2</sub>)<sub>2</sub>(CH<sup>3</sup>COOCCHCOOCH<sub>3</sub>)][B(C<sub>6</sub>H<sub>5</sub>)<sub>4</sub>]'. Together they form a unique fingerprint.

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Physics & Astronomy