Abstract
Lost in rotation: The concise strategy of the first enantioselective total synthesis of bismurrayaquinone A utilized traceless stereochemical exchange to form an enantioenriched biphenyl core that was elaborated in a bidirectional manner to the natural product. Observed racemization on an unsuccessful initial route prompted studies into the configurational stability of bismurrayaquinone A and related biquinones.
Original language | English (US) |
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Pages (from-to) | 9931-9934 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 50 |
Issue number | 42 |
DOIs | |
State | Published - Oct 10 2011 |
Keywords
- alkaloids
- axial chirality
- biquinones
- natural products
- total synthesis
ASJC Scopus subject areas
- General Chemistry
- Catalysis
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CCDC 835897: Experimental Crystal Structure Determination
Konkol, L. C. (Creator), Guo, F. (Creator), Sarjeant, A. A. (Creator) & Thomson, R. J. (Creator), Cambridge Crystallographic Data Centre, 2011
DOI: 10.5517/ccx1tf5, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccx1tf5&sid=DataCite
Dataset
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CCDC 829783: Experimental Crystal Structure Determination
Konkol, L. C. (Creator), Guo, F. (Creator) & Thomson, R. J. (Creator), Cambridge Crystallographic Data Centre, 2011
DOI: 10.5517/ccwvg6c, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccwvg6c&sid=DataCite
Dataset
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CCDC 829781: Experimental Crystal Structure Determination
Konkol, L. C. (Creator), Guo, F. (Creator), Sarjeant, A. A. (Creator) & Thomson, R. J. (Creator), Cambridge Crystallographic Data Centre, 2011
DOI: 10.5517/ccwvg49, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccwvg49&sid=DataCite
Dataset