ENDOR Spectroscopy Reveals the “Free” 5′-Deoxyadenosyl Radical in a Radical SAM Enzyme Active Site Actually is Chaperoned by Close Interaction with the Methionine-Bound [4Fe-4S]2+ Cluster

Hao Yang, Madeline B. Ho, Maike N. Lundahl, Martín A. Mosquera, William E. Broderick, Joan B. Broderick*, Brian M. Hoffman*

*Corresponding author for this work

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Biochemistry, Genetics and Molecular Biology

Chemistry