Enhanced gas sorption properties and unique behavior toward liquid water in a pillared-paddlewheel metal-organic framework transmetalated with Ni(II)

Olga Karagiaridi; Wojciech Bury; David Fairen-Jimenez; Christopher E. Wilmer; Amy A. Sarjeant; Joseph T. Hupp; Omar K. Farha

doi:10.1021/ic501467w

Enhanced gas sorption properties and unique behavior toward liquid water in a pillared-paddlewheel metal-organic framework transmetalated with Ni(II)

Olga Karagiaridi, Wojciech Bury, David Fairen-Jimenez, Christopher E. Wilmer, Amy A. Sarjeant, Joseph T. Hupp^*, Omar K. Farha

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

The synthesis of a permanently porous pillared-paddlewheel metal-organic framework (MOF) was achieved through transmetalation of Zn(II) with Ni(II). The MOF can be treated with liquid water, leading to the reversible displacement of 50% of its pillars by water molecules and resulting in a most unusual crystalline and permanently porous structure.

Original language	English (US)
Pages (from-to)	10432-10436
Number of pages	5
Journal	Inorganic chemistry
Volume	53
Issue number	19
DOIs	https://doi.org/10.1021/ic501467w
State	Published - Oct 6 2014

ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry

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10.1021/ic501467w

Cite this

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abstract = "The synthesis of a permanently porous pillared-paddlewheel metal-organic framework (MOF) was achieved through transmetalation of Zn(II) with Ni(II). The MOF can be treated with liquid water, leading to the reversible displacement of 50% of its pillars by water molecules and resulting in a most unusual crystalline and permanently porous structure.",

author = "Olga Karagiaridi and Wojciech Bury and David Fairen-Jimenez and Wilmer, {Christopher E.} and Sarjeant, {Amy A.} and Hupp, {Joseph T.} and Farha, {Omar K.}",

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AU - Karagiaridi, Olga

AU - Bury, Wojciech

AU - Fairen-Jimenez, David

AU - Wilmer, Christopher E.

AU - Sarjeant, Amy A.

AU - Hupp, Joseph T.

AU - Farha, Omar K.

PY - 2014/10/6

Y1 - 2014/10/6

N2 - The synthesis of a permanently porous pillared-paddlewheel metal-organic framework (MOF) was achieved through transmetalation of Zn(II) with Ni(II). The MOF can be treated with liquid water, leading to the reversible displacement of 50% of its pillars by water molecules and resulting in a most unusual crystalline and permanently porous structure.

AB - The synthesis of a permanently porous pillared-paddlewheel metal-organic framework (MOF) was achieved through transmetalation of Zn(II) with Ni(II). The MOF can be treated with liquid water, leading to the reversible displacement of 50% of its pillars by water molecules and resulting in a most unusual crystalline and permanently porous structure.

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JF - Inorganic chemistry

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Enhanced gas sorption properties and unique behavior toward liquid water in a pillared-paddlewheel metal-organic framework transmetalated with Ni(II)

Abstract

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CCDC 1009334: Experimental Crystal Structure Determination

Cite this

Enhanced gas sorption properties and unique behavior toward liquid water in a pillared-paddlewheel metal-organic framework transmetalated with Ni(II)

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

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Datasets

CCDC 1009334: Experimental Crystal Structure Determination

Cite this