The synthesis of a permanently porous pillared-paddlewheel metal-organic framework (MOF) was achieved through transmetalation of Zn(II) with Ni(II). The MOF can be treated with liquid water, leading to the reversible displacement of 50% of its pillars by water molecules and resulting in a most unusual crystalline and permanently porous structure.
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
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Karagiaridi, O. (Creator), Bury, W. (Creator), Fairen-Jimenez, D. (Creator), Wilmer, C. E. (Creator), Sarjeant, A. A. (Creator), Hupp, J. T. (Creator), Farha, O. K. (Creator), Hupp, J. T. (Creator) & Farha, O. K. (Creator), Cambridge Crystallographic Data Centre, 2015