Enhanced photovoltaic performance and stability with a new type of hollow 3D perovskite {en}FASnI3

Weijun Ke, Constantinos C. Stoumpos, Menghua Zhu, Lingling Mao, Ioannis Spanopoulos, Jian Liu, Oleg Y. Kontsevoi, Michelle Chen, Debajit Sarma, Yongbo Zhang, Michael R. Wasielewski, Mercouri G. Kanatzidis*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

325 Scopus citations


Perovskite solar cells have revolutionized the fabrication of solution-processable solar cells. The presence of lead in the devices makes this technology less attractive, and alternative metals in perovskites are being researched as suitable alternatives. We demonstrate a new type of tin-based perovskite absorber that incorporates both ethylenediammonium (en) and formamidinium (FA), forming new materials of the type {en}FASnI3. The threedimensional ASnI3 structure is stable only with methylammonium, FA, and Cs cations, and the bandgap can be tuned with solid solutions, such as ASnI3-xBrx. We show that en can serve as a new A cation capable of achieving marked increases in the bandgap without the need for solid solutions. The en introduces a new bandgap tuning mechanism that arises from massive Schottky style defects. In addition, incorporation of the en cation in the structure markedly increases the air stability and improves the photoelectric properties of the tin-based perovskite absorbers. Our best-performing {en}FASnI3 solar cell has the highest efficiency of 7.14%, which is achieved for a lead-free perovskite cell, and retains 96%of its initial efficiency after aging over 1000 hours with encapsulation. Our results introduce a new approach for improving the performance and stability of tin-based, lead-free perovskite solar cells.

Original languageEnglish (US)
Article numbere1701293
JournalScience Advances
Issue number8
StatePublished - Aug 2017

ASJC Scopus subject areas

  • General


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