Abstract
A novel Mn2+⋯Bi3+ heterobimetallic complex, featuring the closest Mn⋯Bi interaction for a paramagnetic molecular species, exhibits unusually large axial zero-field splitting. We attribute this enhancement to the proximity of Mn2+ to a heavy main group element, namely, bismuth.
Original language | English (US) |
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Pages (from-to) | 11394-11397 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 52 |
Issue number | 76 |
DOIs | |
State | Published - Jan 1 2016 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- General Chemistry
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
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CCDC 1497013: Experimental Crystal Structure Determination
Pearson, T. J. (Creator), Fataftah, M. S. (Creator) & Freedman, D. E. (Creator), Cambridge Crystallographic Data Centre, 2016
DOI: 10.5517/ccdc.csd.cc1m7rrc, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1m7rrc&sid=DataCite
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