Enhancing heterogeneous catalysis through cooperative hybrid organic-inorganic interfaces

Justin M. Notestein; Alexander Katz

doi:10.1002/chem.200501152

Enhancing heterogeneous catalysis through cooperative hybrid organic-inorganic interfaces

Justin M. Notestein, Alexander Katz^*

^*Corresponding author for this work

Chemical and Biological Engineering

Research output: Contribution to journal › Article › peer-review

215 Scopus citations

Abstract

Active-site/surface cooperativity can enhance heterogeneous organic and organometallic catalysis. We review the powerful role of the solid surface in this context for generating local acidity and, as an inner-sphere ligand, for stabilizing immobilized supramolecular assemblies and unsaturated organometallic complexes that are often unstable in solution.

Original language	English (US)
Pages (from-to)	3954-3965
Number of pages	12
Journal	Chemistry - A European Journal
Volume	12
Issue number	15
DOIs	https://doi.org/10.1002/chem.200501152
State	Published - May 15 2006

Keywords

Cooperativity
Enantioselectivity
Heterogeneous catalysis
Organic-inorganic hybrid composites
Surface chemistry

ASJC Scopus subject areas

Chemistry(all)

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10.1002/chem.200501152

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title = "Enhancing heterogeneous catalysis through cooperative hybrid organic-inorganic interfaces",

abstract = "Active-site/surface cooperativity can enhance heterogeneous organic and organometallic catalysis. We review the powerful role of the solid surface in this context for generating local acidity and, as an inner-sphere ligand, for stabilizing immobilized supramolecular assemblies and unsaturated organometallic complexes that are often unstable in solution.",

keywords = "Cooperativity, Enantioselectivity, Heterogeneous catalysis, Organic-inorganic hybrid composites, Surface chemistry",

author = "Notestein, {Justin M.} and Alexander Katz",

year = "2006",

month = may,

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doi = "10.1002/chem.200501152",

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T1 - Enhancing heterogeneous catalysis through cooperative hybrid organic-inorganic interfaces

AU - Notestein, Justin M.

AU - Katz, Alexander

PY - 2006/5/15

Y1 - 2006/5/15

N2 - Active-site/surface cooperativity can enhance heterogeneous organic and organometallic catalysis. We review the powerful role of the solid surface in this context for generating local acidity and, as an inner-sphere ligand, for stabilizing immobilized supramolecular assemblies and unsaturated organometallic complexes that are often unstable in solution.

AB - Active-site/surface cooperativity can enhance heterogeneous organic and organometallic catalysis. We review the powerful role of the solid surface in this context for generating local acidity and, as an inner-sphere ligand, for stabilizing immobilized supramolecular assemblies and unsaturated organometallic complexes that are often unstable in solution.

KW - Cooperativity

KW - Enantioselectivity

KW - Heterogeneous catalysis

KW - Organic-inorganic hybrid composites

KW - Surface chemistry

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U2 - 10.1002/chem.200501152

DO - 10.1002/chem.200501152

M3 - Article

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AN - SCOPUS:33646811188

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SP - 3954

EP - 3965

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

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ER -

Enhancing heterogeneous catalysis through cooperative hybrid organic-inorganic interfaces

Abstract

Keywords

ASJC Scopus subject areas

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