Abstract
Active-site/surface cooperativity can enhance heterogeneous organic and organometallic catalysis. We review the powerful role of the solid surface in this context for generating local acidity and, as an inner-sphere ligand, for stabilizing immobilized supramolecular assemblies and unsaturated organometallic complexes that are often unstable in solution.
Original language | English (US) |
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Pages (from-to) | 3954-3965 |
Number of pages | 12 |
Journal | Chemistry - A European Journal |
Volume | 12 |
Issue number | 15 |
DOIs | |
State | Published - May 15 2006 |
Keywords
- Cooperativity
- Enantioselectivity
- Heterogeneous catalysis
- Organic-inorganic hybrid composites
- Surface chemistry
ASJC Scopus subject areas
- Chemistry(all)