Ethylene Oxidation on a Supported Liquid-Phase Wacker Catalyst

I. Sine Shaw; Joshua S Dranoff; John B. Butt

doi:10.1021/ie00078a007

Ethylene Oxidation on a Supported Liquid-Phase Wacker Catalyst

I. Sine Shaw, Joshua S Dranoff, John B. Butt

Chemical and Biological Engineering

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The oxidation of ethylene to acetaldehyde with a supported liquid-phase (SLP) Wacker catalyst has been investigated. The active phase of the catalyst, a chlorinated solution of PdCl₂, CuCl₂, and Cu(NO₃)₂, was supported on three aluminas of differing texture. The reaction was studied in the temperature range 40-80 ¯C as a function of the catalyst liquid loading. A unimodal size distribution was found desirable in optimizing overall activity, and maximum activity was obtained for a liquid loading of about 0.1 volume liquid catalyst phase/volume pores. Kinetic studies in excess oxygen suggest that the reaction is approximately first order in ethylene. Catalyst deactivation is probably related to a loss of Cl^- during the reaction cycle.

Original language	English (US)
Pages (from-to)	935-942
Number of pages	8
Journal	Industrial and Engineering Chemistry Research
Volume	27
Issue number	6
DOIs	https://doi.org/10.1021/ie00078a007
State	Published - May 1 1988

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Industrial and Manufacturing Engineering

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abstract = "The oxidation of ethylene to acetaldehyde with a supported liquid-phase (SLP) Wacker catalyst has been investigated. The active phase of the catalyst, a chlorinated solution of PdCl2, CuCl2, and Cu(NO3)2, was supported on three aluminas of differing texture. The reaction was studied in the temperature range 40-80 ¯C as a function of the catalyst liquid loading. A unimodal size distribution was found desirable in optimizing overall activity, and maximum activity was obtained for a liquid loading of about 0.1 volume liquid catalyst phase/volume pores. Kinetic studies in excess oxygen suggest that the reaction is approximately first order in ethylene. Catalyst deactivation is probably related to a loss of Cl- during the reaction cycle.",

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AU - Sine Shaw, I.

AU - Dranoff, Joshua S

AU - Butt, John B.

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N2 - The oxidation of ethylene to acetaldehyde with a supported liquid-phase (SLP) Wacker catalyst has been investigated. The active phase of the catalyst, a chlorinated solution of PdCl2, CuCl2, and Cu(NO3)2, was supported on three aluminas of differing texture. The reaction was studied in the temperature range 40-80 ¯C as a function of the catalyst liquid loading. A unimodal size distribution was found desirable in optimizing overall activity, and maximum activity was obtained for a liquid loading of about 0.1 volume liquid catalyst phase/volume pores. Kinetic studies in excess oxygen suggest that the reaction is approximately first order in ethylene. Catalyst deactivation is probably related to a loss of Cl- during the reaction cycle.

AB - The oxidation of ethylene to acetaldehyde with a supported liquid-phase (SLP) Wacker catalyst has been investigated. The active phase of the catalyst, a chlorinated solution of PdCl2, CuCl2, and Cu(NO3)2, was supported on three aluminas of differing texture. The reaction was studied in the temperature range 40-80 ¯C as a function of the catalyst liquid loading. A unimodal size distribution was found desirable in optimizing overall activity, and maximum activity was obtained for a liquid loading of about 0.1 volume liquid catalyst phase/volume pores. Kinetic studies in excess oxygen suggest that the reaction is approximately first order in ethylene. Catalyst deactivation is probably related to a loss of Cl- during the reaction cycle.

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Ethylene Oxidation on a Supported Liquid-Phase Wacker Catalyst

Abstract

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