Exceptional molecular hyperpolarizabilities in twisted π-electron system chromophores

Hu Kang*, Antonio Facchetti, Peiwang Zhu, Hua Jiang, Yu Yang, Elena Cariati, Stefania Righetto, Renata Ugo, Cristiano Zuccaccia, Alceo Macchioni, Charlotte L. Stern, Zhifu Liu, Seng Tiong Ho, Tobin J. Marks

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

127 Scopus citations

Abstract

(Chemical Equation Presented) Nonlinear optics: Twisted π-electron system electrooptic (EO) chromophores with exceptional molecular hyperpolarizabilities (-488 000×10-48 esu at 1907 nm) were designed and synthesized. Crystallographic analysis reveals large twist angles and a highly charge-separated zwitterionic ground state. Experiments on poled host-guest polymers containing these chromophores show them to be promising candidates for EO applications.

Original languageEnglish (US)
Pages (from-to)7922-7925
Number of pages4
JournalAngewandte Chemie - International Edition
Volume44
Issue number48
DOIs
StatePublished - Dec 9 2005

Keywords

  • Chromophores
  • Electrooptics
  • Nonlinear optics
  • Zwitterions
  • pi systems

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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